Diamide-based fullerosteroidal and disteroidal  rotaxanes: solvent-induced macrocycle translocation and/or unthreading
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The synthesis, characterization and behaviour of two novel Leigh-type amide rotaxanes are reported. NMR study shows that fullerosteroidal and disteroidal rotaxanes occur in a peptide co-conformation in CDCl3. [D-6]DMSO induces fast unthreading of disteroidal rotaxane, which includes steroid co-conformers as intermediates. On the other hand, fullerosteroidal rotaxane undergoes predominantly a shuttling process occupying the stacked co-conformation, whereas unthreading is very slow in comparison with its disteroidal analogue (25% after 7 days). Moreover, organogelation and self-organization properties were studied. It was found that disteroidal rotaxane is an organogelator and its SEM image shows that it forms a branched film-like network in a PhMe/EtOAc 1 : 1 mixture.
Извор:RSC Advances, 2016, 6, 43, 37246-37253
- Royal Soc Chemistry, Cambridge