The sequential extraction procedure of the European Community Bureau of Reference (BCR) was applied for the fractionation of Cd, Cr, Cu, Ni, Pb, Zn, Fe, Mn, and V in the Serbian river sediments. The aim of this paper was to describe a new approach in detection of anthropogenic elements in sediments, related to the Serbian river courses in order to assess their metal contamination. For sediment pollution evaluation, the risk assessment code (RAC) and the secondary phase enrichment factor (K-SPEF) were used. Metal fractionation showed more easily mobilized forms predominant for copper, zinc, cadmium, manganese, and lead, which can be one of the indicators for anthropogenic source input. Chromium, nickel, iron, and vanadium found in the residual fraction indicate these metals may be an indicator for natural sources input. Based on RAC classification, results of sediments show no risk (Cr and V), low risk (Ni, Pb, and Fe), medium risk (Cu), high risk (Cd and Zn), and very high risk (Mn). T...he mean values of K-SPEF were Cd > Cu > Zn > Ni > Mn > Pb > Fe > Cr > V, decreasing scale of no to moderately severe enrichment. The sediments were found to be contaminated by heavy metals to various extents, mostly Cd, Cu, and Zn. Research has shown the importance of K-SPEF in quantifying degree of metal enrichment in sediments using results of sequential extraction. With the application of this factor, which is not frequently used in the scientific literature, the results obtained with sequential extraction can be used not only for assessment of mobility but also to quantify the metal pollution.
TY - JOUR
AU - Sakan, Sanja
AU - Popović, Aleksandar R.
AU - Anđelković, Ivan
AU - Đorđević, Dragana
PY - 2016
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/2021
AB - The sequential extraction procedure of the European Community Bureau of Reference (BCR) was applied for the fractionation of Cd, Cr, Cu, Ni, Pb, Zn, Fe, Mn, and V in the Serbian river sediments. The aim of this paper was to describe a new approach in detection of anthropogenic elements in sediments, related to the Serbian river courses in order to assess their metal contamination. For sediment pollution evaluation, the risk assessment code (RAC) and the secondary phase enrichment factor (K-SPEF) were used. Metal fractionation showed more easily mobilized forms predominant for copper, zinc, cadmium, manganese, and lead, which can be one of the indicators for anthropogenic source input. Chromium, nickel, iron, and vanadium found in the residual fraction indicate these metals may be an indicator for natural sources input. Based on RAC classification, results of sediments show no risk (Cr and V), low risk (Ni, Pb, and Fe), medium risk (Cu), high risk (Cd and Zn), and very high risk (Mn). The mean values of K-SPEF were Cd > Cu > Zn > Ni > Mn > Pb > Fe > Cr > V, decreasing scale of no to moderately severe enrichment. The sediments were found to be contaminated by heavy metals to various extents, mostly Cd, Cu, and Zn. Research has shown the importance of K-SPEF in quantifying degree of metal enrichment in sediments using results of sequential extraction. With the application of this factor, which is not frequently used in the scientific literature, the results obtained with sequential extraction can be used not only for assessment of mobility but also to quantify the metal pollution.
PB - Springer, Dordrecht
T2 - Environmental Geochemistry and Health
T1 - Aquatic sediments pollution estimate using the metal fractionation, secondary phase enrichment factor calculation, and used statistical methods
VL - 38
IS - 3
SP - 855
EP - 867
DO - 10.1007/s10653-015-9766-0
ER -
@article{
author = "Sakan, Sanja and Popović, Aleksandar R. and Anđelković, Ivan and Đorđević, Dragana",
year = "2016",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/2021",
abstract = "The sequential extraction procedure of the European Community Bureau of Reference (BCR) was applied for the fractionation of Cd, Cr, Cu, Ni, Pb, Zn, Fe, Mn, and V in the Serbian river sediments. The aim of this paper was to describe a new approach in detection of anthropogenic elements in sediments, related to the Serbian river courses in order to assess their metal contamination. For sediment pollution evaluation, the risk assessment code (RAC) and the secondary phase enrichment factor (K-SPEF) were used. Metal fractionation showed more easily mobilized forms predominant for copper, zinc, cadmium, manganese, and lead, which can be one of the indicators for anthropogenic source input. Chromium, nickel, iron, and vanadium found in the residual fraction indicate these metals may be an indicator for natural sources input. Based on RAC classification, results of sediments show no risk (Cr and V), low risk (Ni, Pb, and Fe), medium risk (Cu), high risk (Cd and Zn), and very high risk (Mn). The mean values of K-SPEF were Cd > Cu > Zn > Ni > Mn > Pb > Fe > Cr > V, decreasing scale of no to moderately severe enrichment. The sediments were found to be contaminated by heavy metals to various extents, mostly Cd, Cu, and Zn. Research has shown the importance of K-SPEF in quantifying degree of metal enrichment in sediments using results of sequential extraction. With the application of this factor, which is not frequently used in the scientific literature, the results obtained with sequential extraction can be used not only for assessment of mobility but also to quantify the metal pollution.",
publisher = "Springer, Dordrecht",
journal = "Environmental Geochemistry and Health",
title = "Aquatic sediments pollution estimate using the metal fractionation, secondary phase enrichment factor calculation, and used statistical methods",
volume = "38",
number = "3",
pages = "855-867",
doi = "10.1007/s10653-015-9766-0"
}
Sakan S, Popović AR, Anđelković I, Đorđević D. Aquatic sediments pollution estimate using the metal fractionation, secondary phase enrichment factor calculation, and used statistical methods. Environmental Geochemistry and Health. 2016;38(3):855-867
Sakan, S., Popović, A. R., Anđelković, I.,& Đorđević, D. (2016). Aquatic sediments pollution estimate using the metal fractionation, secondary phase enrichment factor calculation, and used statistical methods.
Environmental Geochemistry and HealthSpringer, Dordrecht., 38(3), 855-867.
https://doi.org/10.1007/s10653-015-9766-0
Sakan Sanja, Popović Aleksandar R., Anđelković Ivan, Đorđević Dragana, "Aquatic sediments pollution estimate using the metal fractionation, secondary phase enrichment factor calculation, and used statistical methods" 38, no. 3 (2016):855-867,
https://doi.org/10.1007/s10653-015-9766-0 .
