dc.creator | Kaluđerović, Goran N. | |
dc.creator | Hernandez-Corroto, Esther | |
dc.creator | Brandt, Wolfgang | |
dc.creator | Zmejkovski, Bojana | |
dc.creator | Gomez-Ruiz, Santiago | |
dc.date.accessioned | 2019-01-30T17:51:40Z | |
dc.date.available | 2019-01-30T17:51:40Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/2014 | |
dc.description.abstract | Four palladium(II) complexes with R-2 edda ligands, dichlorido(O,O-dialkylethylenediamine-N,N'-diacetate)palladium(II) monohydrates, [PdCl2(R(2)edda)].H2O, R=Me, Et, n-Pr, i-Bu, and the new ligand precursor i-Bu(2)edda.2HCl.H2O, O,O-diisobutylethylenediamine-N,N'-diacetate dihydrochloride monohydrate, were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopy, and elemental analysis. DFT calculations were performed for the palladium(II) complexes and a high possibility for isomer formation due to stereogenic N ligand atoms was confirmed. Moreover, DFT simulations revealed energetic profile of isomer formation. Computational outcomes are in agreement with spectroscopic instrumental findings, both strongly indicating a non-stereoselective reaction between selected esters and K-2[PdCl4], forming isomers. [GRAPHICS] | en |
dc.publisher | Taylor & Francis Ltd, Abingdon | |
dc.relation | Ministerio de Economia y Competitividad, Spain - CTQ2012-30762 | |
dc.relation | Universidad Rey Juan Carlos-Banco de Santander - Excellence Group QUINANOAP | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS// | |
dc.rights | restrictedAccess | |
dc.source | Journal of Coordination Chemistry | |
dc.subject | Palladium(II) complexes | en |
dc.subject | R-2 edda ligands | en |
dc.subject | diastereoisomers | en |
dc.subject | DFT | en |
dc.title | Palladium(II) complexes with R-2 edda-derived ligands | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Хернандез-Цоррото, Естхер; Калудеровиц, Горан Н; Змејковски, Бојана; Брандт, Wолфганг; Гомез-Руизб, Сантиаго; | |
dc.citation.volume | 69 | |
dc.citation.issue | 8 | |
dc.citation.spage | 1337 | |
dc.citation.epage | 1345 | |
dc.citation.other | 69(8): 1337-1345 | |
dc.citation.rank | M22 | |
dc.identifier.doi | 10.1080/00958972.2016.1168519 | |
dc.identifier.scopus | 2-s2.0-84964034012 | |
dc.identifier.wos | 000375481700004 | |
dc.type.version | publishedVersion | |