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Palladium(II) complexes with R-2 edda-derived ligands

Authorized Users Only
2016
Authors
Kaluđerović, Goran N.
Hernandez-Corroto, Esther
Brandt, Wolfgang
Zmejkovski, Bojana
Gomez-Ruiz, Santiago
Article (Published version)
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Abstract
Four palladium(II) complexes with R-2 edda ligands, dichlorido(O,O-dialkylethylenediamine-N,N'-diacetate)palladium(II) monohydrates, [PdCl2(R(2)edda)].H2O, R=Me, Et, n-Pr, i-Bu, and the new ligand precursor i-Bu(2)edda.2HCl.H2O, O,O-diisobutylethylenediamine-N,N'-diacetate dihydrochloride monohydrate, were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopy, and elemental analysis. DFT calculations were performed for the palladium(II) complexes and a high possibility for isomer formation due to stereogenic N ligand atoms was confirmed. Moreover, DFT simulations revealed energetic profile of isomer formation. Computational outcomes are in agreement with spectroscopic instrumental findings, both strongly indicating a non-stereoselective reaction between selected esters and K-2[PdCl4], forming isomers. [GRAPHICS]
Keywords:
Palladium(II) complexes / R-2 edda ligands / diastereoisomers / DFT
Source:
Journal of Coordination Chemistry, 2016, 69, 8, 1337-1345
Publisher:
  • Taylor & Francis Ltd, Abingdon
Funding / projects:
  • Ministerio de Economia y Competitividad, Spain - CTQ2012-30762
  • Universidad Rey Juan Carlos-Banco de Santander - Excellence Group QUINANOAP
  • Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)

DOI: 10.1080/00958972.2016.1168519

ISSN: 0095-8972

WoS: 000375481700004

Scopus: 2-s2.0-84964034012
[ Google Scholar ]
2
2
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/2014
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Kaluđerović, Goran N.
AU  - Hernandez-Corroto, Esther
AU  - Brandt, Wolfgang
AU  - Zmejkovski, Bojana
AU  - Gomez-Ruiz, Santiago
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2014
AB  - Four palladium(II) complexes with R-2 edda ligands, dichlorido(O,O-dialkylethylenediamine-N,N'-diacetate)palladium(II) monohydrates, [PdCl2(R(2)edda)].H2O, R=Me, Et, n-Pr, i-Bu, and the new ligand precursor i-Bu(2)edda.2HCl.H2O, O,O-diisobutylethylenediamine-N,N'-diacetate dihydrochloride monohydrate, were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopy, and elemental analysis. DFT calculations were performed for the palladium(II) complexes and a high possibility for isomer formation due to stereogenic N ligand atoms was confirmed. Moreover, DFT simulations revealed energetic profile of isomer formation. Computational outcomes are in agreement with spectroscopic instrumental findings, both strongly indicating a non-stereoselective reaction between selected esters and K-2[PdCl4], forming isomers. [GRAPHICS]
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Palladium(II) complexes with R-2 edda-derived ligands
VL  - 69
IS  - 8
SP  - 1337
EP  - 1345
DO  - 10.1080/00958972.2016.1168519
ER  - 
@article{
author = "Kaluđerović, Goran N. and Hernandez-Corroto, Esther and Brandt, Wolfgang and Zmejkovski, Bojana and Gomez-Ruiz, Santiago",
year = "2016",
abstract = "Four palladium(II) complexes with R-2 edda ligands, dichlorido(O,O-dialkylethylenediamine-N,N'-diacetate)palladium(II) monohydrates, [PdCl2(R(2)edda)].H2O, R=Me, Et, n-Pr, i-Bu, and the new ligand precursor i-Bu(2)edda.2HCl.H2O, O,O-diisobutylethylenediamine-N,N'-diacetate dihydrochloride monohydrate, were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopy, and elemental analysis. DFT calculations were performed for the palladium(II) complexes and a high possibility for isomer formation due to stereogenic N ligand atoms was confirmed. Moreover, DFT simulations revealed energetic profile of isomer formation. Computational outcomes are in agreement with spectroscopic instrumental findings, both strongly indicating a non-stereoselective reaction between selected esters and K-2[PdCl4], forming isomers. [GRAPHICS]",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Palladium(II) complexes with R-2 edda-derived ligands",
volume = "69",
number = "8",
pages = "1337-1345",
doi = "10.1080/00958972.2016.1168519"
}
Kaluđerović, G. N., Hernandez-Corroto, E., Brandt, W., Zmejkovski, B.,& Gomez-Ruiz, S.. (2016). Palladium(II) complexes with R-2 edda-derived ligands. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 69(8), 1337-1345.
https://doi.org/10.1080/00958972.2016.1168519
Kaluđerović GN, Hernandez-Corroto E, Brandt W, Zmejkovski B, Gomez-Ruiz S. Palladium(II) complexes with R-2 edda-derived ligands. in Journal of Coordination Chemistry. 2016;69(8):1337-1345.
doi:10.1080/00958972.2016.1168519 .
Kaluđerović, Goran N., Hernandez-Corroto, Esther, Brandt, Wolfgang, Zmejkovski, Bojana, Gomez-Ruiz, Santiago, "Palladium(II) complexes with R-2 edda-derived ligands" in Journal of Coordination Chemistry, 69, no. 8 (2016):1337-1345,
https://doi.org/10.1080/00958972.2016.1168519 . .

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