Palladium(II) complexes with R-2 edda-derived ligands
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2016
Authors
Kaluđerović, Goran N.
Hernandez-Corroto, Esther
Brandt, Wolfgang
Zmejkovski, Bojana

Gomez-Ruiz, Santiago

Article (Published version)

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Four palladium(II) complexes with R-2 edda ligands, dichlorido(O,O-dialkylethylenediamine-N,N'-diacetate)palladium(II) monohydrates, [PdCl2(R(2)edda)].H2O, R=Me, Et, n-Pr, i-Bu, and the new ligand precursor i-Bu(2)edda.2HCl.H2O, O,O-diisobutylethylenediamine-N,N'-diacetate dihydrochloride monohydrate, were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopy, and elemental analysis. DFT calculations were performed for the palladium(II) complexes and a high possibility for isomer formation due to stereogenic N ligand atoms was confirmed. Moreover, DFT simulations revealed energetic profile of isomer formation. Computational outcomes are in agreement with spectroscopic instrumental findings, both strongly indicating a non-stereoselective reaction between selected esters and K-2[PdCl4], forming isomers. [GRAPHICS]
Keywords:
Palladium(II) complexes / R-2 edda ligands / diastereoisomers / DFTSource:
Journal of Coordination Chemistry, 2016, 69, 8, 1337-1345Publisher:
- Taylor & Francis Ltd, Abingdon
Funding / projects:
- Ministerio de Economia y Competitividad, Spain - CTQ2012-30762
- Universidad Rey Juan Carlos-Banco de Santander - Excellence Group QUINANOAP
- Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)
DOI: 10.1080/00958972.2016.1168519
ISSN: 0095-8972
WoS: 000375481700004
Scopus: 2-s2.0-84964034012
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IHTMTY - JOUR AU - Kaluđerović, Goran N. AU - Hernandez-Corroto, Esther AU - Brandt, Wolfgang AU - Zmejkovski, Bojana AU - Gomez-Ruiz, Santiago PY - 2016 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2014 AB - Four palladium(II) complexes with R-2 edda ligands, dichlorido(O,O-dialkylethylenediamine-N,N'-diacetate)palladium(II) monohydrates, [PdCl2(R(2)edda)].H2O, R=Me, Et, n-Pr, i-Bu, and the new ligand precursor i-Bu(2)edda.2HCl.H2O, O,O-diisobutylethylenediamine-N,N'-diacetate dihydrochloride monohydrate, were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopy, and elemental analysis. DFT calculations were performed for the palladium(II) complexes and a high possibility for isomer formation due to stereogenic N ligand atoms was confirmed. Moreover, DFT simulations revealed energetic profile of isomer formation. Computational outcomes are in agreement with spectroscopic instrumental findings, both strongly indicating a non-stereoselective reaction between selected esters and K-2[PdCl4], forming isomers. [GRAPHICS] PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Palladium(II) complexes with R-2 edda-derived ligands VL - 69 IS - 8 SP - 1337 EP - 1345 DO - 10.1080/00958972.2016.1168519 ER -
@article{ author = "Kaluđerović, Goran N. and Hernandez-Corroto, Esther and Brandt, Wolfgang and Zmejkovski, Bojana and Gomez-Ruiz, Santiago", year = "2016", abstract = "Four palladium(II) complexes with R-2 edda ligands, dichlorido(O,O-dialkylethylenediamine-N,N'-diacetate)palladium(II) monohydrates, [PdCl2(R(2)edda)].H2O, R=Me, Et, n-Pr, i-Bu, and the new ligand precursor i-Bu(2)edda.2HCl.H2O, O,O-diisobutylethylenediamine-N,N'-diacetate dihydrochloride monohydrate, were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopy, and elemental analysis. DFT calculations were performed for the palladium(II) complexes and a high possibility for isomer formation due to stereogenic N ligand atoms was confirmed. Moreover, DFT simulations revealed energetic profile of isomer formation. Computational outcomes are in agreement with spectroscopic instrumental findings, both strongly indicating a non-stereoselective reaction between selected esters and K-2[PdCl4], forming isomers. [GRAPHICS]", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Palladium(II) complexes with R-2 edda-derived ligands", volume = "69", number = "8", pages = "1337-1345", doi = "10.1080/00958972.2016.1168519" }
Kaluđerović, G. N., Hernandez-Corroto, E., Brandt, W., Zmejkovski, B.,& Gomez-Ruiz, S.. (2016). Palladium(II) complexes with R-2 edda-derived ligands. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 69(8), 1337-1345. https://doi.org/10.1080/00958972.2016.1168519
Kaluđerović GN, Hernandez-Corroto E, Brandt W, Zmejkovski B, Gomez-Ruiz S. Palladium(II) complexes with R-2 edda-derived ligands. in Journal of Coordination Chemistry. 2016;69(8):1337-1345. doi:10.1080/00958972.2016.1168519 .
Kaluđerović, Goran N., Hernandez-Corroto, Esther, Brandt, Wolfgang, Zmejkovski, Bojana, Gomez-Ruiz, Santiago, "Palladium(II) complexes with R-2 edda-derived ligands" in Journal of Coordination Chemistry, 69, no. 8 (2016):1337-1345, https://doi.org/10.1080/00958972.2016.1168519 . .