Претраживање
Приказ резултата 1-2 од 2
Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings
(American Chemical Society (ACS), 2007)
Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.
Ring-closing metathesis/fragmentation route to geometrically defined medium-ring cycloalkenes: Total synthesis of (+/-)-periplanone C
(American Chemical Society (ACS), 2004)
The combination of alkene metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium-ring cycloalkenes. The versatility of this method is demonstrated by the total synthesis of Periplanone C, a ...