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Stereoselective Construction of Fluorinated Quaternary Stereogenic Centers via an Organocatalytic Asymmetric exo-Selective Diels-Alder Reaction in the Presence of Water
(USA : American Chemical Society, 2022)
A catalytic, asymmetric Diels-Alder reaction of α-fluoro α,β-unsaturated aldehydes and cyclopentadiene was developed using diarylprolinol silyl ether as an organocatalyst. The reaction proceeds in toluene with trifluoroacetic ...
Water: new aspect of hydrogen bonding in the solid state
(International Union of Crystallography (IUCr), 2022)
All water–water contacts in the crystal structures from the Cambridge Structural
Database with dOO 4.0 A˚ have been found. These contacts were analysed on
the basis of their geometries and interaction energies from ...