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Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium
(Royal Society of Chemistry, 1985)
The reaction-field theory based on dipole and quadrupole interactions has been generalized, yielding an expression for the energy as a function of point dipole and quadrupole position and orientation within a spherical ...
Synthesis, structure, and reactions of secosteroids containing a medium-sized ring. Part 17. Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 3-tosylates
(Royal Society of Chemistry, 1980)
Kinetic measurements of the solvolysis of (Z)-3α- and (Z)-3β-, and (E)-3α- and (E)-3β-tosyloxy-5,10-secocholest-1(10)-en-5-ones in buffered aqueous acetone (90 : 10 v/v) reveal that the (Z)-3α-, (E)-3α-, and (E)-3β-tosylates ...