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Acid-catalyzed rearrangement of some steroidal isoxazolidines
(Elsevier, 1999)
Acid-catalyzed reaction of the steroidal Δ 1 -unsaturated 3β,5β- epoxyimino compound 2 and Δ 3 -unsaturated 1β,5β-epoxyimino products 3 and 7, results in intramolecular rearrangement involving the N-CH 3 group to give the ...
Lead tetraacetate oxidation of saturated aliphatic alcohols.-III. Unbranched primary and secondary alcohols
(Elsevier, 1965)
The action of lead tetraacetate, in benzene solution, on various unbranched primary and secondary aliphatic alcohols containing 4 to 12 carbon atoms has been investigated and the ratio of carbonyl compounds, cyclic ethers ...
The conformational equilibrium of 1,3-dichloro-5-methylcyclohexane
(Elsevier, 1981)
Two of the stereoisomers of the title compound were prepared and their dipole moments were measured. For the r-1,c-3-dichloro-t-5-methylcyclohexane, the free energy difference between conformers with axial-axial (aa) and ...
Intramolecular cyclization of 3β-acetoxy-16-picolinylidene-5-androsten-17-one by catalytic hydrogenation
(Elsevier, 1970)
Intramolecular cyclization by catalytic hydrogenation of 3β-acetoxy-16-picolinylidene-5-androsten-17-one (IV) (80° and 50-60 atm of hydrogen pressure over Pd/C as catalyst) gives rise to the formation of two cyclic products, ...
A novel pimara-8(9),15-diene from lycopus europaeus
(Pergamon Press, 1985)
Identification of a novel trioxygenated Δ8(9),15_ pimaric acid methyl ester from plant species Lycopus europaeus by means of two-dimensional 1H NMR spectroscopy (COSY and NOESY) is reported. © 1985.
The reaction of lead tetra-acetate with some unbranched α,ω-diols
(Elsevier, 1969)
Unbranched α,ω-diols are mainly converted by means of lead tetra-acetate in refluxing benzene to the corresponding ethers of di-α-tetrahydrofuryl, di-α-tetrahydropyryl and/or α-tetrahydrofuryl-α′-tetrahydropyryl type. Thus, ...
Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives
(Oxford : Pergamon-Elsevier Science Ltd, 2013)
Trithiaazapentalene derivatives were prepared by the reaction of 2-alkylidene-4-oxothiazolidines with Lawesson's reagent. They are classified as two structurally different trithiaazapentalene compounds that have different ...
Lead tetraacetate oxidation of saturated aliphatic alcohols-IV. The formation of six-membered cyclic ethers
(Elsevier, 1965)
The lead tetraacetate oxidation of saturated aliphatic alcohols, with structures which do not permit 1,5-cyclization, gave tetrahydropyran derivatives in yields not exceeding 16%. The formation of a small amount of the ...
Reactions with lead tetraacetate-I. Oxidation of saturated aliphatic alcohols part 1
(Elsevier, 1964)
When oxidized with lead tetraacetate 1-heptanol and 1-octanol undergo cyclization to give as major products the corresponding 2-alkyltetrahydrofurans, accompanied by a small amount of the isomeric tetrahydropyran derivatives. ...
Transformations of 2-alkylidene-4-oxothiazolidine vinyl bromides initiated by bromophilic attack of neutral and anionic nucleophiles
(Oxford : Pergamon-Elsevier Science Ltd, 2010)
Vinyl bromides derived from 2-alkylidene-4-oxothiazolidines represent a class of vinyl halides, which readily undergo a bromophilic attack by a range of nucleophiles. With Ph(3)P, AcS(-), CN(-), I(-), F(-), Ac(2)CH(-) and ...