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Fundamental aspects of pulsating current metal electrodeposition IX: The prevention of spongy deposit formation on inert substrates
(Elsevier, 1984)
It is shown that spongy deposits are obtained under d.c. conditions and that compact deposits are obtained in pulsating current (PC) deposition with high pause-to-pulse ratios at the same average current density and ...
Oxygen reduction on the Au (311) electrode surface in alkaline electrolyte
(Elsevier, 1988)
Oxygen reduction was studied for the first time using a single crystal electrode in a rotating disc-ring arrangement. The Au (311) surface shows a complex behaviour, with a very high activity in certain potential regions. ...
The electrocatalytic properties of the oxides of noble metals in the electro-oxidation of some organic molecules
(Elsevier, 1997)
The electro-oxidation of organic compounds on gold and silver electrodes can occur either in a potential range more negative than that where the metal oxides are formed or within the more positive range where the surface ...
Kinetics and mechanism of deposition of zinc from zincate in concentrated alkali hydroxide solutions
(Elsevier, 1976)
Galvanostatic investigation has been carried out of the kinetics of the reaction on zinc amalgam hanging mercury drop immersed in alkaline zincate solutions at KOH concentrations ranging from 1 to 14 normal. Three kinds ...
Structural effects in electrocatalysis: oxidation of formaldehyde on gold and platinum single crystal electrodes in alkaline solution
(Elsevier, 1984)
The oxidation of formaldehyde in sodium hydroxide solution has been studied on platinum and gold single crystal electrodes with the (111), (110) and (100) orientations. There is apparently no structural sensitivity of this ...
Activation of aluminium in chloride containing solutions
(Elsevier, 1988)
Galvanostatic transients were recorded for anodic dissolution of high purity aluminium in neutral chloride solutions. All transients, except at very low current densities (below 50 μA cm-2), are characterized by an overshoot ...
Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction
(Elsevier, 1987)
Some of the well-known criteria for analysing rotating disk measurements have been examined. It has been shown that for reactions with complex mechanisms the number of electrons exchanged per reactant is a function of the ...
Electrosorption of hydrogen and sulphuric acid anions on single-crystal platinum stepped surfaces. Part I. The [110] zone
(Elsevier, 1988)
The adsorption of hydrogen and sulphuric acid anions has been studied on single-crystal platinum stepped surfaces from the [110] zone. Both processes depend on the orientation of the electrode surface. The multiple states ...
Nickel oxide on mechanochemically synthesized TiO2–CeO2: photocatalytic and electrochemical activity
(Springer, 2021)
This paper presents a new two-step method for the synthesis of NiO/TiO2–CeO2 semiconductors, which implies, the first, the mechanochemical synthesis of TiO2–CeO2 support, and the second is the doping of different NiO ...
The critical overpotential for zinc dendrite formation
(Kluwer Academic Publishers, 1979)
The critical overpotential for zinc dendrite growth is determined as 173 mV by the method described by Popov et al. [1]. It was shown that this procedure can be applied successfully to metal deposition processes when there ...