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Stereochemistry and conformations of natural 1,2-epoxy-guaianolides based on 1D and 2D NMR data and semiempirical calculations
(Magnetic Resonance in Chemistry, 2008)
From detailed study of ID and 2D NMR spectra of ten natural 1,2-epoxyguaianolides (bis-1,2:3,4-epoxyguaianolides and guaianolide-1,2- epoxychlorohydrins), we identified general spectral traits helpful for stereochemical ...
EPR spin-trapping and spin-probing spectroscopy in assessing antioxidant properties: Example on extracts of catkin, leaves, and spiny burs of castanea sativa
(Food Biophysics, 2009)
Electron paramagnetic resonance (EPR) spin-trapping and spin-probing techniques were applied to determine antioxidant activity of extracts of catkin, leaves, and spiny burs of Castanea sativa against physiologically relevant ...
Oxidation of n-hexane over Pt and Cu-Co oxide catalysts supported on a thin-film zirconia/stainless steel carrier
(Catalysis Communications, 2008)
The complete oxidation of n-hexane in air over a stainless steel foil (SS) coated with a thin film of ZrO2 (SS/ZrO2), SS/ZrO2/Pt, SS/ZrO2/La2O3/CuCo and SS/ZrO2/La2O3/CuCo/Pt catalysts has been investigated. The ZrO2 films ...
The kinetics of ethanol adsorption from the aqueous phase onto zeolite NaZSM-5
(Springer, New York, 2008)
The kinetics of the isothermal adsorption of ethanol from an aqueous solution onto a hydrophobic zeolite of the NaZSM-5 type in the temperature range 298-333 K was investigated. Specific shape parameters of the adsorption ...
Synthesis of the first thiazolidine-condensed five-, six-, and seven-membered heterocycles via cyclization of vinylogous N-acyliminium ions
(Synlett, 2009)
Synthesis of new thiazolidine-fused five-, six-, and seven-membered heterocycles through vinylogous N-acyliminium ion-cyclization sequence, involving positions 3 and 4 of the thiazolidine ring, is described. The formation ...
Reactively sputtered Ni, Ni(N) and Ni3N films: Structural, electrical and magnetic properties
(Elsevier, 2009)
Nickel thin films were deposited on glass substrates at different N2 gas contents using a dc triode sputtering deposition system. Triode configuration was used to deposit nanostructured thin films with preferred orientation ...
Reactions of ortho-substituted α,α-dibromoacetophenones with nucleophiles: first examples of combined carbophilic and bromophilic attack on C-Br bonds
(Oxford : Pergamon-Elsevier Science Ltd, 2009)
An efficient method for the formation of α-carbonyl-monosubstituted acetophenones from ortho-methoxy- and ortho-hydroxy-α,α-dibromoacetophenones and a range of selected nucleophiles, occurring via a carbophilic ...
The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure
(Elsevier, 2000)
The influence of the aging time of RuO2 and TiO2 sols used for the preparation of (40% RuO2+60% TiO2)/Ti anodes by the sol-gel procedure on the electrochemical properties and behavior for the chlorine evolution reaction ...
Activation Energies as the Validity Criterion of a Model for Complex Reactions that can be in Oscillatory States
(Belgrade: ETRAN – Society for electronics, telecommunication, computing, automatics and nuclear engineering, 2007)
Modeling of any complex reaction system is a difficult task. If the system under examination can be in various oscillatory dynamic states, the apparent activation energies corresponding to different pathways may be of ...
Multifractal analysis of the UV/VIS spectra of malignant ascites: Confirmation of the diagnostic validity of a clinically evaluated spectral analysis
(Physica A: Statistical Mechanics and its Applications, 2008)
Multifractal (MF) approach was applied for the analysis of ultraviolet/visible (UV/VIS) spectra as an independent confirmation of the diagnostic efficacy of UV/VIS spectral analysis of intraperitoneal fluids, ascites, taken ...