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dc.creatorStanković, Dalibor
dc.creatorSamphao, Anchalee
dc.creatorDojčinović, Biljana
dc.creatorKalcher, Kurt
dc.date.accessioned2019-01-30T17:51:18Z
dc.date.available2019-01-30T17:51:18Z
dc.date.issued2016
dc.identifier.issn1318-0207
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1997
dc.description.abstractThis work presents the electrochemical behavior of levodopa (L-DOPA), at boron-doped diamond (BDD) electrodes, using cycling voltammetry (CV), in Britton-Robinson (BR) buffer solution, and application of the proposed electrode for the determination of L-DOPA in extracts from the seeds of velvet bean (Mucuna prurita Hook or Mucuna pruriens (L.) DC.). L-DOPA provides a well-defined and single oval-shape oxidation peak at +0.8 V vs. Ag/AgCl (3 M KCl) reference electrode in BR buffer solution at pH 3.0. Experimental parameters, such as pH of supporting electrolyte and square wave voltammetry (SWV) operating parameters (frequency and modulation amplitude) were optimized. The effect of possible interferences was evaluated. Under optimal conditions the detection limit of the developed method was 0.8 mu M and the calibration curve for L-DOPA was linear in the range from 2 to 100 mu M. The proposed method was successfully applied to the determination of L-DOPA in an extract from the seeds of Mucuna prurita. The obtained result was in good agreement with obtained by photometry with 2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid (ABTS). The developed approach can be beneficial for the quantification of L-DOPA using a BDD electrode as up-to-date potential alternative sensor for electroanalytical applications.en
dc.publisherSlovensko Kemijsko Drustvo, Ljubljana
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172030/RS//
dc.relationAsea UniNet
dc.relationJoinEU-SEE-Penta Erasmus Mundus scholarship
dc.rightsopenAccess
dc.sourceActa Chimica Slovenica
dc.subjectL-DOPAen
dc.subjectboron-doped diamond electrodeen
dc.subjectsquare wave voltammetryen
dc.titleRapid Electrochemical Method for the Determination of L-DOPA in Extract From the Seeds of Mucuna Pruritaen
dc.typearticle
dc.rights.licenseBY
dcterms.abstractДојчиновић, Биљана; Калцхер, Курт; Сампхао, Aнцхалее; Станковиц, Далибор М.;
dc.citation.volume63
dc.citation.issue2
dc.citation.spage220
dc.citation.epage226
dc.citation.other63(2): 220-226
dc.citation.rankM23
dc.identifier.pmid27333543
dc.identifier.doi10.17344/acsi.2015.1541
dc.identifier.rcubConv_3629
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8425/1995.pdf
dc.identifier.scopus2-s2.0-84975259896
dc.identifier.wos000388252900003
dc.type.versionpublishedVersion


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