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dc.creatorMaksin, Danijela
dc.creatorNastasović, Aleksandra
dc.creatorMaksin, Tatjana N
dc.creatorSandić, Zvjezdana P.
dc.creatorLoos, Katja
dc.creatorEkmeščić, Bojana
dc.creatorOnjia, Antonije E.
dc.date.accessioned2019-01-30T17:50:28Z
dc.date.available2019-01-30T17:50:28Z
dc.date.issued2016
dc.identifier.issn0367-598X
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1957
dc.description.abstractSynthesis of an unconventional resin based on 4-vinylpyridine (4-VP) and its Cu(II) sorption behavior were studied. Three samples of macroporous crosslinked poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) (P4VPE) with different porosity parameters were prepared by suspension copolymerization by varying the n-heptane amount in the inert component. The samples were characterized by mercury porosimetry, elemental analysis and X-ray photoelectron spectroscopy (XPS). The sorption of P4VPE for Cu(II) ions, determined under non-competitive conditions, was relatively rapid, i.e., the maximum capacity was reached within 30 min. The maximum experimental sorption capacity for the sample with the highest values of pore diameter and specific pore volume (sample 3, Q(eq) = 89 mg g(-1)) was 17.5 times higher than for the sample with the lowest values of pore diameter and specific pore volume (sample 1, Q(eq) = 5.1 mg g(-1)). Since the values for pyridine content in all P4VPE samples were almost the same, it was concluded that the porosity parameters have predominant influence on Cu(II) sorption rates on P4VPE. The sorption behavior and the rate-controlling mechanisms were analyzed using six kinetic models (pseudo-first order, pseudo-second order, Elovich, intraparticle diffusion, Bangham and Boyd models). XPS study clarified the nature of the formed P4VPE-Cu(II) species.en
dc.publisherAssociation of Chemical Engineers of Serbia
dc.relationinfo:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/37021/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS//
dc.rightsopenAccess
dc.sourceHemijska industrija
dc.subject4-vinylpyridineen
dc.subjectmacroporous copolymeren
dc.subjectsorption kineticsen
dc.subjectXPSen
dc.titleCu(II) immobilization onto a one-step synthesized poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) resin: Kinetics and XPS analysisen
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractОњиа, Aнтоније Е; Лоос, Катја; Сандиц, Звјездана П; Екмешчић, Бојана; Максин, Татјана Н; Максин, Данијела Д; Настасовић, Aлександра;
dc.citation.volume70
dc.citation.issue1
dc.citation.spage9
dc.citation.epage19
dc.citation.other70(1): 9-19
dc.citation.rankM23
dc.identifier.doi10.2298/HEMIND141203007M
dc.identifier.rcubConv_3506
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8387/1955.pdf
dc.identifier.scopus2-s2.0-84960444146
dc.identifier.wos000372733800002
dc.type.versionpublishedVersion


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