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dc.creatorLović, Jelena
dc.creatorMijin, Dušan
dc.creatorJovanović, Mica B.
dc.creatorGlavaski, Olivera S
dc.creatorZeremski, Tijana
dc.creatorPetrović, Slobodan D.
dc.creatorAvramov Ivić, Milka
dc.date.accessioned2019-01-30T17:50:14Z
dc.date.available2019-01-30T17:50:14Z
dc.date.issued2016
dc.identifier.issn1631-0748
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1944
dc.description.abstractTebuconazole, a pesticide that presents risks for ecosystems, groundwater and human health, was degraded on a gold electrode as the catalyst in 0.05 M NaHCO3 using cyclic voltammetry (CV). First, tebuconazole was characterized on the gold electrode using CV and square wave voltammetry (SWV). The gold electrode, being highly sensitive, provided linear relationships (currents vs. concentrations) in the range: (0.076-0.76 mu mol dm(-3)). Based on the CV measurements, the investigated process is irreversible and diffusion controlled. The observed catalytic role of the Au electrode in the oxidation of tebuconazole and the data obtained from CV and SWV provided the experimental conditions for the degradation of tebuconazole. The degradation was performed by continuous cycling followed by gas chromatography mass spectroscopy (GC MS) analysis. This enabled the catalytic elimination of tebuconazole for 60 min, which promoted the use of a gold electrode as the catalyst for the degradation of environmental pollutants. The scheme of the possible mechanism of tebuconazole degradation is given.en
dc.publisherElsevier France-Editions Scientifiques Medicales Elsevier, Paris
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.rightsrestrictedAccess
dc.sourceComptes Rendus Chimie
dc.subjectCatalytic degradationen
dc.subjectTebuconazoleen
dc.subjectGold electrodeen
dc.subjectCV voltammetryen
dc.subjectGC-MS analysisen
dc.titleAn investigation of tebuconazole degradation using a gold electrodeen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЗеремски, Тијана М; Мијин, Дусан З; Ловић, Јелена; Aврамов Ивић, Милка; Петровић, Слободан Д.; Главаски, Оливера С; Јовановиц, Мица Б;
dc.citation.volume19
dc.citation.issue5
dc.citation.spage639
dc.citation.epage645
dc.citation.other19(5): 639-645
dc.citation.rankM22
dc.identifier.doi10.1016/j.crci.2016.01.014
dc.identifier.rcubConv_3608
dc.identifier.scopus2-s2.0-84959263685
dc.identifier.wos000385785100012
dc.type.versionpublishedVersion


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