Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure
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2005
Authors
Panić, Vladimir
Dekanski, Aleksandar

Gojković, Snežana Lj.

Milonjić, Slobodan K.

Mišković-Stanković, Vesna

Nikolic, B
Article (Published version)

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The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcano (R) XC-72 R with solid phase of RuOxHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate... an in-depth capacitance distribution through the composite layer. It was found that Nafion (R) layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface.
Keywords:
carbon supported ruthenium oxide / cyclic voltammetry / electrochemical impedance spectroscopy / forced hydrolysis / RuO2 sol / scanning electron microscopy / supercapacitorsSource:
Current Research in Advanced Materials and Processes, 2005, 494, 235-240Publisher:
- Trans Tech Publications Ltd, Durnten-Zurich
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IHTMTY - JOUR AU - Panić, Vladimir AU - Dekanski, Aleksandar AU - Gojković, Snežana Lj. AU - Milonjić, Slobodan K. AU - Mišković-Stanković, Vesna AU - Nikolic, B PY - 2005 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/193 AB - The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcano (R) XC-72 R with solid phase of RuOxHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate an in-depth capacitance distribution through the composite layer. It was found that Nafion (R) layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface. PB - Trans Tech Publications Ltd, Durnten-Zurich T2 - Current Research in Advanced Materials and Processes T1 - Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure VL - 494 SP - 235 EP - 240 DO - 10.4028/www.scientific.net/MSF.494.235 ER -
@article{ author = "Panić, Vladimir and Dekanski, Aleksandar and Gojković, Snežana Lj. and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolic, B", year = "2005", abstract = "The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcano (R) XC-72 R with solid phase of RuOxHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate an in-depth capacitance distribution through the composite layer. It was found that Nafion (R) layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface.", publisher = "Trans Tech Publications Ltd, Durnten-Zurich", journal = "Current Research in Advanced Materials and Processes", title = "Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure", volume = "494", pages = "235-240", doi = "10.4028/www.scientific.net/MSF.494.235" }
Panić, V., Dekanski, A., Gojković, S. Lj., Milonjić, S. K., Mišković-Stanković, V.,& Nikolic, B.. (2005). Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure. in Current Research in Advanced Materials and Processes Trans Tech Publications Ltd, Durnten-Zurich., 494, 235-240. https://doi.org/10.4028/www.scientific.net/MSF.494.235
Panić V, Dekanski A, Gojković SL, Milonjić SK, Mišković-Stanković V, Nikolic B. Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure. in Current Research in Advanced Materials and Processes. 2005;494:235-240. doi:10.4028/www.scientific.net/MSF.494.235 .
Panić, Vladimir, Dekanski, Aleksandar, Gojković, Snežana Lj., Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolic, B, "Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure" in Current Research in Advanced Materials and Processes, 494 (2005):235-240, https://doi.org/10.4028/www.scientific.net/MSF.494.235 . .