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dc.creatorLončarević, Davor
dc.creatorČupić, Željko
dc.date.accessioned2019-01-30T17:12:59Z
dc.date.available2019-01-30T17:12:59Z
dc.date.issued2005
dc.identifier.issn0255-5476
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/190
dc.description.abstractPoly(4-vinylpyridine-co-divinylbenzene)-Co2+ was characterized using infrared spectroscopy (IR), thermogravinietric analysis (TG-DTA), N-2-physisorption and polarography. Thermal analysis suggests sufficient thermal stability of the polymer support, under reaction conditions. From polarography measurements, the Co2+ content on polymer-supported catalysts is estimated and it was proved that no significant leaching occurred during the activity tests. At the molecular level, FTIR of P4VP-DVB-Co2+ reveals that the pyridine nitrogen lone pair coordinates to the metal center in the polymeric complex. The obtained P4VP-DVB-Co2+ catalysts performed interesting catalytic activity in reaction of the cyclohexane oxidation with air, indicating that increasing Co2+ content lowers the initiation temperature and raises the decomposition of cyclohexylhydroperoxide.en
dc.publisherTrans Tech Publications Ltd, Durnten-Zurich
dc.rightsrestrictedAccess
dc.sourceCurrent Research in Advanced Materials and Processes
dc.subjectcyclohexane oxidation by airen
dc.subjectpolymer supported catalysten
dc.subjectpoly(4-vinylpyridine-co-divinylbenzene)-Co-2en
dc.titleCharacterization and catalytic activity of poly(4-vinylpyridine-co-divinylbenzene)-Co2+ complexen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЦипиц, З; Лончаревић, Давор;
dc.citation.volume494
dc.citation.spage363
dc.citation.epage368
dc.citation.other494: 363-368
dc.citation.rankM23
dc.identifier.doi10.4028/www.scientific.net/MSF.494.363
dc.identifier.rcubConv_2337
dc.identifier.wos000230985800060
dc.type.versionpublishedVersion


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