Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy
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2016
Authors
Jegdić, BoreŽivković, Ljiljana S.
Popić, Jovan P.
Rogan, Jelena R.
Bajat, Jelena
Mišković-Stanković, Vesna
Article (Published version)
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In this study, corrosion protection efficiency of undoped epoxy and epoxy coating doped with cerium on aluminum alloy AA6060 is evaluated over prolonged exposure to 3wt% NaCl solution by electrochemical impedance spectroscopy (EIS). Different amounts of Ce(NO3)(3) are added into the epoxy suspension used for the cataphoretic deposition. Suspension stability is characterized by zeta potential and particle size values. Water content and thermal stability of the coatings were determined by thermogravimetric analysis. Insufficient corrosion stability, very close to that of undoped epoxy, is revealed for the coating with 1mM Ce. Higher cerium doping contributes to a significant increase in corrosion stability (2-3 orders of magnitude greater charge-transfer resistance). Epoxy coating doped with 5mM Ce displays a pronounced self-healing ability and the best corrosion protection and adhesion, owing to evenly distributed cerium precipitates on the aluminum surface. In the case of 10mM Ce-doped... coating, the formation of Ce clusters and higher porosity causes a certain lowering of the protective ability. EIS measurements on epoxy coating with artificial defect confirm these findings.
Keywords:
aluminum / cataphoretic deposition / cerium doping / corrosion / EIS / epoxy coatingSource:
Materials and Corrosion-Werkstoffe und Korrosion, 2016, 67, 11, 1173-1184Publisher:
- Wiley-V C H Verlag Gmbh, Weinheim
Funding / projects:
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)
- Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine (RS-45012)
DOI: 10.1002/maco.201608827
ISSN: 0947-5117
WoS: 000387145500006
Scopus: 2-s2.0-84963527532
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IHTMTY - JOUR AU - Jegdić, Bore AU - Živković, Ljiljana S. AU - Popić, Jovan P. AU - Rogan, Jelena R. AU - Bajat, Jelena AU - Mišković-Stanković, Vesna PY - 2016 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1886 AB - In this study, corrosion protection efficiency of undoped epoxy and epoxy coating doped with cerium on aluminum alloy AA6060 is evaluated over prolonged exposure to 3wt% NaCl solution by electrochemical impedance spectroscopy (EIS). Different amounts of Ce(NO3)(3) are added into the epoxy suspension used for the cataphoretic deposition. Suspension stability is characterized by zeta potential and particle size values. Water content and thermal stability of the coatings were determined by thermogravimetric analysis. Insufficient corrosion stability, very close to that of undoped epoxy, is revealed for the coating with 1mM Ce. Higher cerium doping contributes to a significant increase in corrosion stability (2-3 orders of magnitude greater charge-transfer resistance). Epoxy coating doped with 5mM Ce displays a pronounced self-healing ability and the best corrosion protection and adhesion, owing to evenly distributed cerium precipitates on the aluminum surface. In the case of 10mM Ce-doped coating, the formation of Ce clusters and higher porosity causes a certain lowering of the protective ability. EIS measurements on epoxy coating with artificial defect confirm these findings. PB - Wiley-V C H Verlag Gmbh, Weinheim T2 - Materials and Corrosion-Werkstoffe und Korrosion T1 - Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy VL - 67 IS - 11 SP - 1173 EP - 1184 DO - 10.1002/maco.201608827 ER -
@article{ author = "Jegdić, Bore and Živković, Ljiljana S. and Popić, Jovan P. and Rogan, Jelena R. and Bajat, Jelena and Mišković-Stanković, Vesna", year = "2016", abstract = "In this study, corrosion protection efficiency of undoped epoxy and epoxy coating doped with cerium on aluminum alloy AA6060 is evaluated over prolonged exposure to 3wt% NaCl solution by electrochemical impedance spectroscopy (EIS). Different amounts of Ce(NO3)(3) are added into the epoxy suspension used for the cataphoretic deposition. Suspension stability is characterized by zeta potential and particle size values. Water content and thermal stability of the coatings were determined by thermogravimetric analysis. Insufficient corrosion stability, very close to that of undoped epoxy, is revealed for the coating with 1mM Ce. Higher cerium doping contributes to a significant increase in corrosion stability (2-3 orders of magnitude greater charge-transfer resistance). Epoxy coating doped with 5mM Ce displays a pronounced self-healing ability and the best corrosion protection and adhesion, owing to evenly distributed cerium precipitates on the aluminum surface. In the case of 10mM Ce-doped coating, the formation of Ce clusters and higher porosity causes a certain lowering of the protective ability. EIS measurements on epoxy coating with artificial defect confirm these findings.", publisher = "Wiley-V C H Verlag Gmbh, Weinheim", journal = "Materials and Corrosion-Werkstoffe und Korrosion", title = "Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy", volume = "67", number = "11", pages = "1173-1184", doi = "10.1002/maco.201608827" }
Jegdić, B., Živković, L. S., Popić, J. P., Rogan, J. R., Bajat, J.,& Mišković-Stanković, V.. (2016). Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy. in Materials and Corrosion-Werkstoffe und Korrosion Wiley-V C H Verlag Gmbh, Weinheim., 67(11), 1173-1184. https://doi.org/10.1002/maco.201608827
Jegdić B, Živković LS, Popić JP, Rogan JR, Bajat J, Mišković-Stanković V. Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy. in Materials and Corrosion-Werkstoffe und Korrosion. 2016;67(11):1173-1184. doi:10.1002/maco.201608827 .
Jegdić, Bore, Živković, Ljiljana S., Popić, Jovan P., Rogan, Jelena R., Bajat, Jelena, Mišković-Stanković, Vesna, "Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy" in Materials and Corrosion-Werkstoffe und Korrosion, 67, no. 11 (2016):1173-1184, https://doi.org/10.1002/maco.201608827 . .