Chromatographic methods in determination of the soil-water partition coefficient
Abstract
The soil-water partition coefficient normalized to the soil organic carbon content (K-OC) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K-OC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K-OC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well ...as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.
Keywords:
High-performance liquid chromatography / soil thin-layer chromatography / soil-column chromatography / soil-water partition coefficient (K-OC) / thin-layer chromatographySource:
Journal of Liquid Chromatography & Related Technologies, 2016, 39, 5-6, 249-256Publisher:
- Taylor & Francis Inc, Philadelphia
Funding / projects:
- Structure-properties relationships of natural and synthetic molecules and their metal complexes (RS-172017)
DOI: 10.1080/10826076.2016.1163173
ISSN: 1082-6076
WoS: 000378000800003
Scopus: 2-s2.0-84969248930
Collections
Institution/Community
IHTMTY - JOUR AU - Andrić, Filip AU - Šegan, Sandra AU - Tešić, Živoslav AU - Milojković-Opsenica, Dušanka PY - 2016 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1861 AB - The soil-water partition coefficient normalized to the soil organic carbon content (K-OC) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K-OC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K-OC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals. PB - Taylor & Francis Inc, Philadelphia T2 - Journal of Liquid Chromatography & Related Technologies T1 - Chromatographic methods in determination of the soil-water partition coefficient VL - 39 IS - 5-6 SP - 249 EP - 256 DO - 10.1080/10826076.2016.1163173 ER -
@article{ author = "Andrić, Filip and Šegan, Sandra and Tešić, Živoslav and Milojković-Opsenica, Dušanka", year = "2016", abstract = "The soil-water partition coefficient normalized to the soil organic carbon content (K-OC) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K-OC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K-OC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.", publisher = "Taylor & Francis Inc, Philadelphia", journal = "Journal of Liquid Chromatography & Related Technologies", title = "Chromatographic methods in determination of the soil-water partition coefficient", volume = "39", number = "5-6", pages = "249-256", doi = "10.1080/10826076.2016.1163173" }
Andrić, F., Šegan, S., Tešić, Ž.,& Milojković-Opsenica, D.. (2016). Chromatographic methods in determination of the soil-water partition coefficient. in Journal of Liquid Chromatography & Related Technologies Taylor & Francis Inc, Philadelphia., 39(5-6), 249-256. https://doi.org/10.1080/10826076.2016.1163173
Andrić F, Šegan S, Tešić Ž, Milojković-Opsenica D. Chromatographic methods in determination of the soil-water partition coefficient. in Journal of Liquid Chromatography & Related Technologies. 2016;39(5-6):249-256. doi:10.1080/10826076.2016.1163173 .
Andrić, Filip, Šegan, Sandra, Tešić, Živoslav, Milojković-Opsenica, Dušanka, "Chromatographic methods in determination of the soil-water partition coefficient" in Journal of Liquid Chromatography & Related Technologies, 39, no. 5-6 (2016):249-256, https://doi.org/10.1080/10826076.2016.1163173 . .