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Chromatographic methods in determination of the soil-water partition coefficient

Authorized Users Only
2016
Authors
Andrić, Filip
Šegan, Sandra
Tešić, Živoslav
Milojković-Opsenica, Dušanka
Article (Published version)
Metadata
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Abstract
The soil-water partition coefficient normalized to the soil organic carbon content (K-OC) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K-OC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K-OC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well ...as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.

Keywords:
High-performance liquid chromatography / soil thin-layer chromatography / soil-column chromatography / soil-water partition coefficient (K-OC) / thin-layer chromatography
Source:
Journal of Liquid Chromatography & Related Technologies, 2016, 39, 5-6, 249-256
Publisher:
  • Taylor & Francis Inc, Philadelphia
Funding / projects:
  • Structure-properties relationships of natural and synthetic molecules and their metal complexes (RS-172017)

DOI: 10.1080/10826076.2016.1163173

ISSN: 1082-6076

WoS: 000378000800003

Scopus: 2-s2.0-84969248930
[ Google Scholar ]
5
3
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/1861
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Andrić, Filip
AU  - Šegan, Sandra
AU  - Tešić, Živoslav
AU  - Milojković-Opsenica, Dušanka
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1861
AB  - The soil-water partition coefficient normalized to the soil organic carbon content (K-OC) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K-OC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K-OC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Journal of Liquid Chromatography & Related Technologies
T1  - Chromatographic methods in determination of the soil-water partition coefficient
VL  - 39
IS  - 5-6
SP  - 249
EP  - 256
DO  - 10.1080/10826076.2016.1163173
ER  - 
@article{
author = "Andrić, Filip and Šegan, Sandra and Tešić, Živoslav and Milojković-Opsenica, Dušanka",
year = "2016",
abstract = "The soil-water partition coefficient normalized to the soil organic carbon content (K-OC) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K-OC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K-OC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Journal of Liquid Chromatography & Related Technologies",
title = "Chromatographic methods in determination of the soil-water partition coefficient",
volume = "39",
number = "5-6",
pages = "249-256",
doi = "10.1080/10826076.2016.1163173"
}
Andrić, F., Šegan, S., Tešić, Ž.,& Milojković-Opsenica, D.. (2016). Chromatographic methods in determination of the soil-water partition coefficient. in Journal of Liquid Chromatography & Related Technologies
Taylor & Francis Inc, Philadelphia., 39(5-6), 249-256.
https://doi.org/10.1080/10826076.2016.1163173
Andrić F, Šegan S, Tešić Ž, Milojković-Opsenica D. Chromatographic methods in determination of the soil-water partition coefficient. in Journal of Liquid Chromatography & Related Technologies. 2016;39(5-6):249-256.
doi:10.1080/10826076.2016.1163173 .
Andrić, Filip, Šegan, Sandra, Tešić, Živoslav, Milojković-Opsenica, Dušanka, "Chromatographic methods in determination of the soil-water partition coefficient" in Journal of Liquid Chromatography & Related Technologies, 39, no. 5-6 (2016):249-256,
https://doi.org/10.1080/10826076.2016.1163173 . .

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