Show simple item record

dc.creatorNikolić, Nebojša
dc.creatorŽivković, Predrag M.
dc.creatorStevanović, Sanja
dc.creatorBranković, Goran
dc.date.accessioned2019-01-30T17:48:24Z
dc.date.available2019-01-30T17:48:24Z
dc.date.issued2016
dc.identifier.issn0352-5139
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1854
dc.description.abstractThe processes of lead electrodeposition from electrolytes of various concentrations of sodium nitrate as the supporting electrolyte have been examined by chronoamperometry and by the scanning electron microscopic (SEM) analysis of deposits obtained in the potentiostatic regime of electrolysis. The good agreement between the diffusion coefficents determined by Cottrell equation and non-linear fitting method was observed. For the first time, the transition from the mixed ohmic-diffusion to the full diffusion control was defined from the analysis of Cottrell equation. The parameters, such as the number density of active sites and the nucleation rate constant, obtained by non-linear fitting method were discussed in accordance with the fact that lead belongs to the group of metals characterized by the high values of the exchange current density. The data obtained by the chronoamperometric analysis were succesfully correlated with morphologies of electrodeposited lead obtained in the different types of electrodeposition control.en
dc.publisherSerbian Chemical Society
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS//
dc.rightsopenAccess
dc.sourceJournal of the Serbian Chemical Society
dc.subjectelectrodepositionen
dc.subjectchronoamperometryen
dc.subjectdiffusionen
dc.subjectCottrell equationen
dc.subjectscanning electron microscope (SEM)en
dc.titleRelationship between the kinetic parameters and morphology of electrochemically deposited leaden
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractСтевановић, Сања; Зивковиц, Предраг М; Бранковиц, Горан; Николић, Небојша;
dc.citation.volume81
dc.citation.issue5
dc.citation.spage553
dc.citation.epage566
dc.citation.other81(5): 553-566
dc.citation.rankM23
dc.identifier.doi10.2298/JSC151218028N
dc.identifier.rcubConv_3561
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8291/1852.pdf
dc.identifier.scopus2-s2.0-84978312805
dc.identifier.wos000379232800007
dc.type.versionpublishedVersion


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record