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dc.creatorTasic, Gordana
dc.creatorMaslak, Veselin
dc.creatorHusinec, Suren
dc.creatorTodorović, Nina
dc.creatorSavić, Vladimir
dc.date.accessioned2019-01-30T17:46:00Z
dc.date.available2019-01-30T17:46:00Z
dc.date.issued2015
dc.identifier.issn0040-4039
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1740
dc.description.abstractThe intramolecular Heck reaction has been examined for the preparation of the core bicyclic structure of corialstonidine. Initial attempts to cyclise a vinyl iodide moiety onto a cyclic allyl alcohol were complicated by various side reactions. However, the corresponding process performed under reductive conditions on a conjugated ketone, obtained from the cyclic allyl alcohol, afforded the desired bicyclo[3.2.1] derivative. This compound possesses the skeletal features of the carbocyclic fragment of corialstonidine and is suitable for further transformations aimed towards the synthesis of the natural product or its derivatives.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172009/RS//
dc.rightsrestrictedAccess
dc.sourceTetrahedron Letters
dc.subjectHeck reactionen
dc.subjectCorialstonidineen
dc.subjectBicyclic ketoneen
dc.titleStudy of the intramolecular Heck reaction: synthesis of the bicyclic core of corialstonidineen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractМаслак, Веселин; Тасиц, Гордана; Хусинец, Сурен; Тодоровић, Нина; Савиц, Владимир;
dc.citation.volume56
dc.citation.issue19
dc.citation.spage2529
dc.citation.epage2532
dc.citation.other56(19): 2529-2532
dc.citation.rankM22
dc.identifier.doi10.1016/j.tetlet.2015.03.129
dc.identifier.rcubConv_3331
dc.identifier.scopus2-s2.0-84937762963
dc.identifier.wos000353751000035
dc.type.versionpublishedVersion


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