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dc.creatorCvetković, Vesna S.
dc.creatorBjelica, Luka J
dc.creatorVukićević, Nataša
dc.creatorJovićević, Jovan N.
dc.date.accessioned2019-01-30T17:44:43Z
dc.date.available2019-01-30T17:44:43Z
dc.date.issued2015
dc.identifier.issn1451-9372
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1681
dc.description.abstractMagnesium was underpotentially deposited on aluminium electrodes from magnesium nitrate-ammonium nitrate melts at temperatures ranging from 390 to 500 K. The electrochemical techniques used were linear sweep voltammetry and potential step. Electrodes were studied by scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD). It was found that reduction processes of nitrate, nitrite and water (when present), in the underpotential range studied, took part simultaneously with magnesium underpotential deposition. Consequently, magnesium UPD reduction and stripping voltammetry peaks were not pronounced and well defined. Nevertheless, EDS, EDX and XRD measurements showed evidence of Mg2Al3, MgAl2 and Al12Mg17 alloys formed by underpotential deposition of magnesium onto aluminium substrate.en
dc.publisherAssociation of the Chemical Engineers of Serbia
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.rightsopenAccess
dc.sourceChemical Industry and Chemical Engineering Quarterly / CICEQ
dc.subjectmagnesium/aluminium alloysen
dc.subjectunderpotential depositionen
dc.subjectmagnesium nitrate meltsen
dc.titleAlloy formation by mg under-potential deposition on al from nitrate meltsen
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractБјелица, Лука Ј; Цветковић, Весна С.; Вукићевић, Наташа; Јовицевиц, Јован Н;
dc.citation.volume21
dc.citation.issue4
dc.citation.spage527
dc.citation.epage536
dc.citation.other21(4): 527-536
dc.citation.rankM23
dc.identifier.doi10.2298/CICEQ141205009C
dc.identifier.rcubConv_3493
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8130/1679.pdf
dc.identifier.scopus2-s2.0-84949795605
dc.identifier.wos000370446400008
dc.type.versionpublishedVersion


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