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dc.creatorStevanović, Sanja
dc.creatorTripković, Dušan
dc.creatorPanić, Vladimir
dc.creatorDekanski, Aleksandar
dc.creatorJovanović, Vladislava M.
dc.date.accessioned2019-01-30T17:41:33Z
dc.date.available2019-01-30T17:41:33Z
dc.date.issued2014
dc.identifier.issn2046-2069
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1530
dc.description.abstractIn previous investigations the physicochemical state of electrochemically activated glassy carbon (GC) has been found to affect the electrochemical activity of GC-supported Pt particles. It has been assumed that carbon functional groups (CFGs) generated by GC anodization are able to renew the Pt surface through bifunctional catalysis. In order to provide evidence for the intimate electrocatalytic relationship between Pt and anodized GC and reveal the cause of CFG-induced enhancement of Pt activity, the dynamic response of Pt black supported on differently anodized GC is analysed in this paper by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) in acidic solution. It was found that the capacitive properties of Pt black are not affected by modest GC anodization, but the pore resistance of the Pt layer is considerably affected. Clear evidence for the promoting influence of activated GC (i.e., CFGs) on the Pt desorption capability toward reverse hydrogen spillover at a Pt/CFGs-decorated GC interface in the Pt double layer region is elucidated by both EIS and CV measurements. The extent of GC anodization influences, in a quite similar way, both reverse hydrogen spillover desorption parameters (gained by EIS and CV) and the methanol oxidation rate as it has influence on the parameters describing the particular state of activated GC itself. Namely, the pore resistance of the Pt layer and GC resistance due to the presence of CFGs the highest when GC was moderately anodized, whereas the charge transfer resistance for hydrogen spillover desorption is the lowest. The CFGs of the anodized GC are able to "permeate" the above-applied Pt layer, thus increasing the Pt/ CFGs-decorated GC interface responsible for the enhancement of Pt electrochemical activity.en
dc.publisherThe Royal Society of Chemistry
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.rightsopenAccess
dc.sourceRSC Advances
dc.titlePlatinum electrocatalyst supported on glassy carbon: a dynamic response analysis of Pt activity promoted by substrate anodizationen
dc.typearticle
dc.rights.licenseBY-NC
dcterms.abstractТрипковић, Душан; Декански, Aлександар; Панић, Владимир; Стевановић, Сања; Јовановић, Владислава;
dc.citation.volume4
dc.citation.issue6
dc.citation.spage3051
dc.citation.epage3059
dc.citation.other4(6): 3051-3059
dc.citation.rankM21
dc.identifier.doi10.1039/c3ra45585h
dc.identifier.rcubConv_3083
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8002/1528.pdf
dc.identifier.scopus2-s2.0-84890628934
dc.identifier.wos000329037100063
dc.type.versionpublishedVersion


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