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Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers

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2014
Authors
Dordevic, Milena
Jeremić, Dejan
Kaluđerović, Goran N.
Gómez-Ruiz, Santiago
Anđelković, Boban D.
Radanović, Dušanka
Brčeski, Ilija
Article (Published version)
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Abstract
Three new 1D coordination polymers, [Pb-2(CH3SO3)(4)(H2O)(2)](n), [Hg(CH3SO3)(2)(H2O)(2)](n) and [Sr(CH3SO3)(2)(H2O)](n), were synthesized as large single crystals. The crystals were analyzed and characterized by the means of X-ray analysis, IR and NMR spectroscopy, elemental analysis and solid state UV-Vis spectroscopy. The formation of 1D polymeric chains in the crystal structures of the title compounds is affected by the various bonding modes of the bridging methanesulfonate groups. The studied compounds showed no decomposition in the air.
Keywords:
Lead(II) / Mercury(II) / Strontium(II) / Methanesulfonates / Spectroscopy
Source:
Polyhedron, 2014, 80, 282-289
Publisher:
  • Pergamon-Elsevier Science Ltd, Oxford
Projects:
  • Mechanistic studies of the reactions of transition metal ion complexes with biologically relevant molecules (RS-172011)
Note:
  • The peer-reviewed version: http://cer.ihtm.bg.ac.rs/handle/123456789/3164

DOI: 10.1016/j.poly.2014.05.056

ISSN: 0277-5387

WoS: 000341348300037

Scopus: 2-s2.0-84905435373
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/1429
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