Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate
Authorized Users Only
2014
Authors
Milenković, Milica R.
Cantoni, Giulia
Bacchi, Alessia

Spasojević, Vojislav

Milenković, Marina

Sladić, Dušan

Krstić, Natalija

Anđelković, Katarina

Article (Published version)

Metadata
Show full item recordAbstract
Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime.
Keywords:
Pd(II) complex / Fe(III) complex / 2-(Diphenylphosphino)benzaldehyde / Hydrazone / X-ray structureSource:
Polyhedron, 2014, 80, 47-52Publisher:
- Oxford : Pergamon-Elsevier Science Ltd
Funding / projects:
DOI: 10.1016/j.poly.2014.01.022
ISSN: 0277-5387
WoS: 000341348300007
Scopus: 2-s2.0-84905501224
Collections
Institution/Community
IHTMTY - JOUR AU - Milenković, Milica R. AU - Cantoni, Giulia AU - Bacchi, Alessia AU - Spasojević, Vojislav AU - Milenković, Marina AU - Sladić, Dušan AU - Krstić, Natalija AU - Anđelković, Katarina PY - 2014 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1423 AB - Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. PB - Oxford : Pergamon-Elsevier Science Ltd T2 - Polyhedron T1 - Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate VL - 80 SP - 47 EP - 52 DO - 10.1016/j.poly.2014.01.022 ER -
@article{ author = "Milenković, Milica R. and Cantoni, Giulia and Bacchi, Alessia and Spasojević, Vojislav and Milenković, Marina and Sladić, Dušan and Krstić, Natalija and Anđelković, Katarina", year = "2014", abstract = "Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime.", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "Polyhedron", title = "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate", volume = "80", pages = "47-52", doi = "10.1016/j.poly.2014.01.022" }
Milenković, M. R., Cantoni, G., Bacchi, A., Spasojević, V., Milenković, M., Sladić, D., Krstić, N.,& Anđelković, K.. (2014). Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. in Polyhedron Oxford : Pergamon-Elsevier Science Ltd., 80, 47-52. https://doi.org/10.1016/j.poly.2014.01.022
Milenković MR, Cantoni G, Bacchi A, Spasojević V, Milenković M, Sladić D, Krstić N, Anđelković K. Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. in Polyhedron. 2014;80:47-52. doi:10.1016/j.poly.2014.01.022 .
Milenković, Milica R., Cantoni, Giulia, Bacchi, Alessia, Spasojević, Vojislav, Milenković, Marina, Sladić, Dušan, Krstić, Natalija, Anđelković, Katarina, "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate" in Polyhedron, 80 (2014):47-52, https://doi.org/10.1016/j.poly.2014.01.022 . .