CER - Central Repository
Institute of Chemistry, Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   CER
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
  •   CER
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram

Authorized Users Only
2014
Authors
Premović, Milena
Minić, Duško
Ćosović, Vladan
Manasijević, Dragan
Živković, Dragana
Article (Published version)
Metadata
Show full item record
Abstract
A phase diagram of the Bi-Ge-Sb ternary system was investigated experimentally by differential thermal analysis (DTA), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), and X-ray powder diffraction (XRD) methods and theoretically by the CALPHAD method. The liquidus projection; invariant equilibria; and three vertical sections, Sb-Bi0.5Ge0.5, Ge-Bi0.5Sb0.5, and Bi-Ge0.5Sb0.5, as well as isothermal sections at 773 K and 373 K (500 A degrees C and 100 A degrees C), were predicted using optimized thermodynamic parameters for constitutive binary systems from the literature. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Predicted isothermal sections at 773 K and 373 K (500 A degrees C and 100 A degrees C) were compared with the results of the SEM-EDS and XRD analysis from this work. In both cases, good agreement between the extrapolated phase diagram and... experimental results was obtained. Alloys from the three studied vertical sections were additionally analyzed using the Brinell hardness test.

Source:
Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science, 2014, 11, 4829-4841
Publisher:
  • Springer, New York
Funding / projects:
  • Advanced multicomponent metal systems and nanostructured materials with diverse functional properties (RS-172037)

DOI: 10.1007/s11661-014-2445-4

ISSN: 1073-5623

WoS: 000341086700017

Scopus: 2-s2.0-84906780117
[ Google Scholar ]
9
9
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/1419
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Premović, Milena
AU  - Minić, Duško
AU  - Ćosović, Vladan
AU  - Manasijević, Dragan
AU  - Živković, Dragana
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1419
AB  - A phase diagram of the Bi-Ge-Sb ternary system was investigated experimentally by differential thermal analysis (DTA), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), and X-ray powder diffraction (XRD) methods and theoretically by the CALPHAD method. The liquidus projection; invariant equilibria; and three vertical sections, Sb-Bi0.5Ge0.5, Ge-Bi0.5Sb0.5, and Bi-Ge0.5Sb0.5, as well as isothermal sections at 773 K and 373 K (500 A degrees C and 100 A degrees C), were predicted using optimized thermodynamic parameters for constitutive binary systems from the literature. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Predicted isothermal sections at 773 K and 373 K (500 A degrees C and 100 A degrees C) were compared with the results of the SEM-EDS and XRD analysis from this work. In both cases, good agreement between the extrapolated phase diagram and experimental results was obtained. Alloys from the three studied vertical sections were additionally analyzed using the Brinell hardness test.
PB  - Springer, New York
T2  - Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science
T1  - Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram
IS  - 11
SP  - 4829
EP  - 4841
DO  - 10.1007/s11661-014-2445-4
ER  - 
@article{
author = "Premović, Milena and Minić, Duško and Ćosović, Vladan and Manasijević, Dragan and Živković, Dragana",
year = "2014",
abstract = "A phase diagram of the Bi-Ge-Sb ternary system was investigated experimentally by differential thermal analysis (DTA), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), and X-ray powder diffraction (XRD) methods and theoretically by the CALPHAD method. The liquidus projection; invariant equilibria; and three vertical sections, Sb-Bi0.5Ge0.5, Ge-Bi0.5Sb0.5, and Bi-Ge0.5Sb0.5, as well as isothermal sections at 773 K and 373 K (500 A degrees C and 100 A degrees C), were predicted using optimized thermodynamic parameters for constitutive binary systems from the literature. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Predicted isothermal sections at 773 K and 373 K (500 A degrees C and 100 A degrees C) were compared with the results of the SEM-EDS and XRD analysis from this work. In both cases, good agreement between the extrapolated phase diagram and experimental results was obtained. Alloys from the three studied vertical sections were additionally analyzed using the Brinell hardness test.",
publisher = "Springer, New York",
journal = "Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science",
title = "Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram",
number = "11",
pages = "4829-4841",
doi = "10.1007/s11661-014-2445-4"
}
Premović, M., Minić, D., Ćosović, V., Manasijević, D.,& Živković, D.. (2014). Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram. in Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science
Springer, New York.(11), 4829-4841.
https://doi.org/10.1007/s11661-014-2445-4
Premović M, Minić D, Ćosović V, Manasijević D, Živković D. Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram. in Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science. 2014;(11):4829-4841.
doi:10.1007/s11661-014-2445-4 .
Premović, Milena, Minić, Duško, Ćosović, Vladan, Manasijević, Dragan, Živković, Dragana, "Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram" in Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science, no. 11 (2014):4829-4841,
https://doi.org/10.1007/s11661-014-2445-4 . .

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

re3dataOpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

re3dataOpenAIRERCUB