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dc.creatorNikolić, Nebojša D.
dc.creatorPopov, Konstantin I.
dc.creatorIvanović, Evica
dc.creatorBranković, Goran
dc.date.accessioned2019-01-30T17:39:13Z
dc.date.available2019-01-30T17:39:13Z
dc.date.issued2014
dc.identifier.issn0352-5139
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1418
dc.description.abstractThe processes of Pb electrodeposition under diffusion control were examined by scanning electron microscopy (SEM) of the formed crystals. The orientation of grains of hexagonal shape formed in the initial stage of electrodeposition strongly affected the final morphology of the Pb crystals. The formation of Pb crystals of the different shape from the same initial shape was discussed in terms of the effect of orientation of initially formed grains on the type of diffusion control. A spherical diffusion layer was formed around the tip of the hexagonal-shaped grain oriented with its tip towards the bulk solution that led to the formation of elongated crystals in the growth process. On the other hand, a cylindrical type of diffusion was responsible for the growth of hexagonal-shaped grains oriented with the lateral side towards the bulk solution. Pb crystals with well-defined sides parallel to the surface area of the macroelectrode were formed under this type of diffusion.en
dc.publisherSerbian Chemical Society
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS//
dc.rightsopenAccess
dc.sourceJournal of the Serbian Chemical Society
dc.subjectelectrodepositionen
dc.subjectleaden
dc.subjectcrystalen
dc.subjectspherical diffusionen
dc.subjectcylindrical diffusionen
dc.subjectscanning electron microscope (SEM)en
dc.titleEffect of the orientation of the initially formed grains on the final morphology of electrodeposited leaden
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractПопов, Константин И.; Бранковиц, Горан; Николић, Небојша; Ивановиц, Евица Р;
dc.citation.volume79
dc.citation.issue8
dc.citation.spage993
dc.citation.epage1005
dc.citation.other79(8): 993-1005
dc.citation.rankM23
dc.identifier.doi10.2298/JSC131211006N
dc.identifier.rcubConv_3202
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/7899/1416.pdf
dc.identifier.scopus2-s2.0-84906654821
dc.identifier.wos000340980700008
dc.type.versionpublishedVersion


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