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Effect of the orientation of the initially formed grains on the final morphology of electrodeposited lead

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2014
1416.pdf (300.2Kb)
Authors
Nikolić, Nebojša D.
Popov, Konstantin I.
Ivanović, Evica
Branković, Goran
Article (Published version)
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Abstract
The processes of Pb electrodeposition under diffusion control were examined by scanning electron microscopy (SEM) of the formed crystals. The orientation of grains of hexagonal shape formed in the initial stage of electrodeposition strongly affected the final morphology of the Pb crystals. The formation of Pb crystals of the different shape from the same initial shape was discussed in terms of the effect of orientation of initially formed grains on the type of diffusion control. A spherical diffusion layer was formed around the tip of the hexagonal-shaped grain oriented with its tip towards the bulk solution that led to the formation of elongated crystals in the growth process. On the other hand, a cylindrical type of diffusion was responsible for the growth of hexagonal-shaped grains oriented with the lateral side towards the bulk solution. Pb crystals with well-defined sides parallel to the surface area of the macroelectrode were formed under this type of diffusion.
Keywords:
electrodeposition / lead / crystal / spherical diffusion / cylindrical diffusion / scanning electron microscope (SEM)
Source:
Journal of the Serbian Chemical Society, 2014, 79, 8, 993-1005
Publisher:
  • Serbian Chemical Society
Funding / projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)

DOI: 10.2298/JSC131211006N

ISSN: 0352-5139

WoS: 000340980700008

Scopus: 2-s2.0-84906654821
[ Google Scholar ]
6
6
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/1418
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Popov, Konstantin I.
AU  - Ivanović, Evica
AU  - Branković, Goran
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1418
AB  - The processes of Pb electrodeposition under diffusion control were examined by scanning electron microscopy (SEM) of the formed crystals. The orientation of grains of hexagonal shape formed in the initial stage of electrodeposition strongly affected the final morphology of the Pb crystals. The formation of Pb crystals of the different shape from the same initial shape was discussed in terms of the effect of orientation of initially formed grains on the type of diffusion control. A spherical diffusion layer was formed around the tip of the hexagonal-shaped grain oriented with its tip towards the bulk solution that led to the formation of elongated crystals in the growth process. On the other hand, a cylindrical type of diffusion was responsible for the growth of hexagonal-shaped grains oriented with the lateral side towards the bulk solution. Pb crystals with well-defined sides parallel to the surface area of the macroelectrode were formed under this type of diffusion.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Effect of the orientation of the initially formed grains on the final morphology of electrodeposited lead
VL  - 79
IS  - 8
SP  - 993
EP  - 1005
DO  - 10.2298/JSC131211006N
ER  - 
@article{
author = "Nikolić, Nebojša D. and Popov, Konstantin I. and Ivanović, Evica and Branković, Goran",
year = "2014",
abstract = "The processes of Pb electrodeposition under diffusion control were examined by scanning electron microscopy (SEM) of the formed crystals. The orientation of grains of hexagonal shape formed in the initial stage of electrodeposition strongly affected the final morphology of the Pb crystals. The formation of Pb crystals of the different shape from the same initial shape was discussed in terms of the effect of orientation of initially formed grains on the type of diffusion control. A spherical diffusion layer was formed around the tip of the hexagonal-shaped grain oriented with its tip towards the bulk solution that led to the formation of elongated crystals in the growth process. On the other hand, a cylindrical type of diffusion was responsible for the growth of hexagonal-shaped grains oriented with the lateral side towards the bulk solution. Pb crystals with well-defined sides parallel to the surface area of the macroelectrode were formed under this type of diffusion.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Effect of the orientation of the initially formed grains on the final morphology of electrodeposited lead",
volume = "79",
number = "8",
pages = "993-1005",
doi = "10.2298/JSC131211006N"
}
Nikolić, N. D., Popov, K. I., Ivanović, E.,& Branković, G.. (2014). Effect of the orientation of the initially formed grains on the final morphology of electrodeposited lead. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 79(8), 993-1005.
https://doi.org/10.2298/JSC131211006N
Nikolić ND, Popov KI, Ivanović E, Branković G. Effect of the orientation of the initially formed grains on the final morphology of electrodeposited lead. in Journal of the Serbian Chemical Society. 2014;79(8):993-1005.
doi:10.2298/JSC131211006N .
Nikolić, Nebojša D., Popov, Konstantin I., Ivanović, Evica, Branković, Goran, "Effect of the orientation of the initially formed grains on the final morphology of electrodeposited lead" in Journal of the Serbian Chemical Society, 79, no. 8 (2014):993-1005,
https://doi.org/10.2298/JSC131211006N . .

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