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dc.creatorPavlović, Miroslav M.
dc.creatorPavlović, Miomir
dc.creatorĆosović, Vladan
dc.creatorBojanić, Vaso
dc.creatorNikolić, Nebojša D.
dc.creatorAleksić, Radoslav
dc.date.accessioned2019-01-30T17:39:11Z
dc.date.available2019-01-30T17:39:11Z
dc.date.issued2014
dc.identifier.issn1452-3981
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/1415
dc.description.abstractComposites based on polymers with conductive fillers have been gaining more significant roles in a variety of technological domains and they are getting in the research focus of numerous studies as a part of growing research trend. Galvanostatically produced copper powder with high values of specific area was used as filler for synthesis of electroconductive composite materials prepared by the compression molding of mixtures of lignocellulose and electrochemically deposited copper powder. This article is concerned with characterization of these composites. Analysis of the most significant properties of prepared composites and its components included measurements of electrical conductivity, impedance spectroscopy (IS) behavior and structural and morphological analysis. Volume fraction of the copper powder was varied from 2.0-29.8% (v/v). The significant increase of the electrical conductivity can be observed as the copper powder content reaches the percolation threshold (PT). It was shown that PT depends on both particle shape and type of spatial distribution. IS measurements have shown that particle morphology having pronounced grain boundaries has great effect on appearance of electric conductive layers. The packaging effect and more pronounced interpartical contact with copper powder particles lead to "movement" of PT, which for the particles LT 45 mu m and highest processing pressure of 27 MPa was 7.2% (v/v). IS response of the composites showed existence of electrical conductive layers, each having different resistivity which increases towards interior of the composite.en
dc.publisherElectrochemical Science Group
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172037/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS//
dc.rightsopenAccess
dc.sourceInternational Journal of Electrochemical Science
dc.subjectimpedance spectroscopyen
dc.subjectelectrolytic copper powderen
dc.subjectlignocelluloseen
dc.subjectcompositeen
dc.titleInfluence of Electrolytic Copper Powder Particle Morphology on Electrical Conductivity of Lignocellulose Composites and Formation of Conductive Pathwaysen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractПавловић, Мирослав М.; Бојаниц, В; Aлексић, Радослав Р.; Николић, Небојша; Ћосовић, Владан; Павловић, Миомир;
dc.citation.volume9
dc.citation.issue12
dc.citation.spage8355
dc.citation.epage8366
dc.citation.other9(12): 8355-8366
dc.citation.rankM23
dc.identifier.rcubhttps://hdl.handle.net/21.15107/rcub_cer_1415
dc.identifier.fulltexthttps://cer.ihtm.bg.ac.rs/bitstream/id/14354/91208355.pdf
dc.identifier.scopus2-s2.0-84908676307
dc.identifier.wos000345261900131
dc.type.versionpublishedVersion


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