The results of calorimetric study of binary Al-Zn system done according to the Oelsen thermodynamic method are presented in this paper. Main thermodynamic properties, including activities, activity coefficients, partial/integral molar Gibbs excess, and mixing energies were determined at 1,000 K. Positive deviation from Raoult law was noticed, with minimal values of Delta G (M) about -3 kJ mol(-1) and maximal values of Delta G (E) about +2 kJ mol(-1). The energetics of mixing in liquid Al-Zn alloys has been analyzed through the study of concentration fluctuation in the long-wavelength limit, and weak affinity between Al and Zn atoms in the system was observed. Differential thermal analysis and light optic microscopy were applied in the frame of characterization of investigated binary alloys and phase diagram examination, and the results obtained were in accordance with available literature data.
Keywords:
Calorimetry / Oelsen method / Al-Zn system / Binary alloys
Source:
Journal of Thermal Analysis and Calorimetry, 2014, 118, 2, 1287-1292
TY - JOUR
AU - Balanović, Ljubiša
AU - Živković, Dragana
AU - Manasijević, Dragan
AU - Minić, Duško
AU - Ćosović, Vladan
AU - Talijan, Nadežda M.
PY - 2014
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1406
AB - The results of calorimetric study of binary Al-Zn system done according to the Oelsen thermodynamic method are presented in this paper. Main thermodynamic properties, including activities, activity coefficients, partial/integral molar Gibbs excess, and mixing energies were determined at 1,000 K. Positive deviation from Raoult law was noticed, with minimal values of Delta G (M) about -3 kJ mol(-1) and maximal values of Delta G (E) about +2 kJ mol(-1). The energetics of mixing in liquid Al-Zn alloys has been analyzed through the study of concentration fluctuation in the long-wavelength limit, and weak affinity between Al and Zn atoms in the system was observed. Differential thermal analysis and light optic microscopy were applied in the frame of characterization of investigated binary alloys and phase diagram examination, and the results obtained were in accordance with available literature data.
PB - Springer, Dordrecht
T2 - Journal of Thermal Analysis and Calorimetry
T1 - Calorimetric investigation of Al-Zn alloys using Oelsen method
VL - 118
IS - 2
SP - 1287
EP - 1292
DO - 10.1007/s10973-014-3990-1
ER -
@article{
author = "Balanović, Ljubiša and Živković, Dragana and Manasijević, Dragan and Minić, Duško and Ćosović, Vladan and Talijan, Nadežda M.",
year = "2014",
abstract = "The results of calorimetric study of binary Al-Zn system done according to the Oelsen thermodynamic method are presented in this paper. Main thermodynamic properties, including activities, activity coefficients, partial/integral molar Gibbs excess, and mixing energies were determined at 1,000 K. Positive deviation from Raoult law was noticed, with minimal values of Delta G (M) about -3 kJ mol(-1) and maximal values of Delta G (E) about +2 kJ mol(-1). The energetics of mixing in liquid Al-Zn alloys has been analyzed through the study of concentration fluctuation in the long-wavelength limit, and weak affinity between Al and Zn atoms in the system was observed. Differential thermal analysis and light optic microscopy were applied in the frame of characterization of investigated binary alloys and phase diagram examination, and the results obtained were in accordance with available literature data.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Calorimetric investigation of Al-Zn alloys using Oelsen method",
volume = "118",
number = "2",
pages = "1287-1292",
doi = "10.1007/s10973-014-3990-1"
}
Balanović, L., Živković, D., Manasijević, D., Minić, D., Ćosović, V.,& Talijan, N. M.. (2014). Calorimetric investigation of Al-Zn alloys using Oelsen method. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 118(2), 1287-1292.
https://doi.org/10.1007/s10973-014-3990-1
Balanović L, Živković D, Manasijević D, Minić D, Ćosović V, Talijan NM. Calorimetric investigation of Al-Zn alloys using Oelsen method. in Journal of Thermal Analysis and Calorimetry. 2014;118(2):1287-1292.
doi:10.1007/s10973-014-3990-1 .
Balanović, Ljubiša, Živković, Dragana, Manasijević, Dragan, Minić, Duško, Ćosović, Vladan, Talijan, Nadežda M., "Calorimetric investigation of Al-Zn alloys using Oelsen method" in Journal of Thermal Analysis and Calorimetry, 118, no. 2 (2014):1287-1292,
https://doi.org/10.1007/s10973-014-3990-1 . .
