Beneficial effect of Ni in pillared bentonite based electrodes on the electrochemical oxidation of phenol
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2014
Authors
Mudrinić, Tihana
Mojović, Zorica

Milutinović Nikolić, Aleksandra

Banković, Predrag

Dojčinović, Biljana

Vukelić, Nikola

Jovanović, Dušan M.
Article (Published version)

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Show full item recordAbstract
The influence of Ni on the electrochemical performance of Fe containing bentonite-based electrode materials was investigated in the electrochemical oxidation of phenol in acidic solution. Clay originated from Mecji Do, Serbia, was submitted to pillaring. Mixed pillaring solutions containing Al3+ and Fe3+ or Al3+, Fe3+ and Ni2+ were used for this purpose. The XRD, chemical and FTIR analysis and nitrogen physisorption at -196 degrees C were used for sample characterization. The electrochemical behavior of the pillared clay-based electrodes was tested by cyclic voltammetry. The results confirmed that the pillaring was successful. The presence of Ni in the electrode material enhanced the electrode stability. It is possible that the presence of Ni restricted the electrode fouling caused by the formation of polymeric products during the electrooxidation of phenol.
Keywords:
Phenol / Electrooxidation / Pillared clay / Electrocatalytic contribution of NiSource:
Electrochimica Acta, 2014, 144, 92-99Publisher:
- Oxford : Pergamon-Elsevier Science Ltd
Funding / projects:
- Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
- Chemical and structural designing of nanomaterials for application in medicine and tissue engineering (RS-172026)
DOI: 10.1016/j.electacta.2014.07.115
ISSN: 0013-4686
WoS: 000343951100013
Scopus: 2-s2.0-84906958505
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IHTMTY - JOUR AU - Mudrinić, Tihana AU - Mojović, Zorica AU - Milutinović Nikolić, Aleksandra AU - Banković, Predrag AU - Dojčinović, Biljana AU - Vukelić, Nikola AU - Jovanović, Dušan M. PY - 2014 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1403 AB - The influence of Ni on the electrochemical performance of Fe containing bentonite-based electrode materials was investigated in the electrochemical oxidation of phenol in acidic solution. Clay originated from Mecji Do, Serbia, was submitted to pillaring. Mixed pillaring solutions containing Al3+ and Fe3+ or Al3+, Fe3+ and Ni2+ were used for this purpose. The XRD, chemical and FTIR analysis and nitrogen physisorption at -196 degrees C were used for sample characterization. The electrochemical behavior of the pillared clay-based electrodes was tested by cyclic voltammetry. The results confirmed that the pillaring was successful. The presence of Ni in the electrode material enhanced the electrode stability. It is possible that the presence of Ni restricted the electrode fouling caused by the formation of polymeric products during the electrooxidation of phenol. PB - Oxford : Pergamon-Elsevier Science Ltd T2 - Electrochimica Acta T1 - Beneficial effect of Ni in pillared bentonite based electrodes on the electrochemical oxidation of phenol VL - 144 SP - 92 EP - 99 DO - 10.1016/j.electacta.2014.07.115 ER -
@article{ author = "Mudrinić, Tihana and Mojović, Zorica and Milutinović Nikolić, Aleksandra and Banković, Predrag and Dojčinović, Biljana and Vukelić, Nikola and Jovanović, Dušan M.", year = "2014", abstract = "The influence of Ni on the electrochemical performance of Fe containing bentonite-based electrode materials was investigated in the electrochemical oxidation of phenol in acidic solution. Clay originated from Mecji Do, Serbia, was submitted to pillaring. Mixed pillaring solutions containing Al3+ and Fe3+ or Al3+, Fe3+ and Ni2+ were used for this purpose. The XRD, chemical and FTIR analysis and nitrogen physisorption at -196 degrees C were used for sample characterization. The electrochemical behavior of the pillared clay-based electrodes was tested by cyclic voltammetry. The results confirmed that the pillaring was successful. The presence of Ni in the electrode material enhanced the electrode stability. It is possible that the presence of Ni restricted the electrode fouling caused by the formation of polymeric products during the electrooxidation of phenol.", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "Electrochimica Acta", title = "Beneficial effect of Ni in pillared bentonite based electrodes on the electrochemical oxidation of phenol", volume = "144", pages = "92-99", doi = "10.1016/j.electacta.2014.07.115" }
Mudrinić, T., Mojović, Z., Milutinović Nikolić, A., Banković, P., Dojčinović, B., Vukelić, N.,& Jovanović, D. M.. (2014). Beneficial effect of Ni in pillared bentonite based electrodes on the electrochemical oxidation of phenol. in Electrochimica Acta Oxford : Pergamon-Elsevier Science Ltd., 144, 92-99. https://doi.org/10.1016/j.electacta.2014.07.115
Mudrinić T, Mojović Z, Milutinović Nikolić A, Banković P, Dojčinović B, Vukelić N, Jovanović DM. Beneficial effect of Ni in pillared bentonite based electrodes on the electrochemical oxidation of phenol. in Electrochimica Acta. 2014;144:92-99. doi:10.1016/j.electacta.2014.07.115 .
Mudrinić, Tihana, Mojović, Zorica, Milutinović Nikolić, Aleksandra, Banković, Predrag, Dojčinović, Biljana, Vukelić, Nikola, Jovanović, Dušan M., "Beneficial effect of Ni in pillared bentonite based electrodes on the electrochemical oxidation of phenol" in Electrochimica Acta, 144 (2014):92-99, https://doi.org/10.1016/j.electacta.2014.07.115 . .