For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.
TY - JOUR
AU - Glavaski, O S
AU - Petrovic, S D
AU - Mijin, Dušan
AU - Jovanović, Mica B.
AU - Dugandzic, A M
AU - Zeremski, Tijana
AU - Avramov Ivić, Milka
PY - 2014
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1393
AB - For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.
PB - Wiley-Blackwell, Malden
T2 - Electroanalysis
T1 - Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes
VL - 26
IS - 9
SP - 1877
EP - 1880
DO - 10.1002/elan.201400249
ER -
@article{
author = "Glavaski, O S and Petrovic, S D and Mijin, Dušan and Jovanović, Mica B. and Dugandzic, A M and Zeremski, Tijana and Avramov Ivić, Milka",
year = "2014",
abstract = "For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.",
publisher = "Wiley-Blackwell, Malden",
journal = "Electroanalysis",
title = "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes",
volume = "26",
number = "9",
pages = "1877-1880",
doi = "10.1002/elan.201400249"
}
Glavaski, O. S., Petrovic, S. D., Mijin, D., Jovanović, M. B., Dugandzic, A. M., Zeremski, T.,& Avramov Ivić, M.. (2014). Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis
Wiley-Blackwell, Malden., 26(9), 1877-1880.
https://doi.org/10.1002/elan.201400249
Glavaski OS, Petrovic SD, Mijin D, Jovanović MB, Dugandzic AM, Zeremski T, Avramov Ivić M. Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis. 2014;26(9):1877-1880.
doi:10.1002/elan.201400249 .
Glavaski, O S, Petrovic, S D, Mijin, Dušan, Jovanović, Mica B., Dugandzic, A M, Zeremski, Tijana, Avramov Ivić, Milka, "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes" in Electroanalysis, 26, no. 9 (2014):1877-1880,
https://doi.org/10.1002/elan.201400249 . .
