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Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes

Authorized Users Only
2014
Authors
Glavaski, O S
Petrovic, S D
Mijin, Dušan
Jovanović, Mica B.
Dugandzic, A M
Zeremski, Tijana
Avramov Ivić, Milka
Article (Published version)
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Abstract
For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.
Keywords:
Cyclic voltammetry / Liquid chromatography / Electrolysis / Liquid mass spectroscopy
Source:
Electroanalysis, 2014, 26, 9, 1877-1880
Publisher:
  • Wiley-Blackwell, Malden
Funding / projects:
  • Study of the Synthesis, Structure and Activity of Natural and Synthetic Organic Compounds (RS-172013)

DOI: 10.1002/elan.201400249

ISSN: 1040-0397

WoS: 000343926700001

Scopus: 2-s2.0-84908205713
[ Google Scholar ]
7
6
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/1393
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Glavaski, O S
AU  - Petrovic, S D
AU  - Mijin, Dušan
AU  - Jovanović, Mica B.
AU  - Dugandzic, A M
AU  - Zeremski, Tijana
AU  - Avramov Ivić, Milka
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1393
AB  - For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.
PB  - Wiley-Blackwell, Malden
T2  - Electroanalysis
T1  - Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes
VL  - 26
IS  - 9
SP  - 1877
EP  - 1880
DO  - 10.1002/elan.201400249
ER  - 
@article{
author = "Glavaski, O S and Petrovic, S D and Mijin, Dušan and Jovanović, Mica B. and Dugandzic, A M and Zeremski, Tijana and Avramov Ivić, Milka",
year = "2014",
abstract = "For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.",
publisher = "Wiley-Blackwell, Malden",
journal = "Electroanalysis",
title = "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes",
volume = "26",
number = "9",
pages = "1877-1880",
doi = "10.1002/elan.201400249"
}
Glavaski, O. S., Petrovic, S. D., Mijin, D., Jovanović, M. B., Dugandzic, A. M., Zeremski, T.,& Avramov Ivić, M.. (2014). Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis
Wiley-Blackwell, Malden., 26(9), 1877-1880.
https://doi.org/10.1002/elan.201400249
Glavaski OS, Petrovic SD, Mijin D, Jovanović MB, Dugandzic AM, Zeremski T, Avramov Ivić M. Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis. 2014;26(9):1877-1880.
doi:10.1002/elan.201400249 .
Glavaski, O S, Petrovic, S D, Mijin, Dušan, Jovanović, Mica B., Dugandzic, A M, Zeremski, Tijana, Avramov Ivić, Milka, "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes" in Electroanalysis, 26, no. 9 (2014):1877-1880,
https://doi.org/10.1002/elan.201400249 . .

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