Electrodeposition of lead from a concentrated nitrate solution was examined by scanning electron microscopy (SEM) and by X-ray diffraction (XRD) analysis of the obtained powder particles. Single crystals of the (111) preferred orientation were formed at a low overpotential by ohmic controlled electrodeposition. Irregular crystals, needle-like and fern-like dendrites, predominantly of the (111) preferred orientation, were formed at high overpotentials (the diffusion control of the electrodeposition). The ratio of Pb crystallites oriented in the (200), (220), (311) and (331) planes increased with increasing electrodeposition overpotential. The correlation between the morphologies and crystallographic structures of the lead deposits was discussed by the consideration of general characteristics of growth layers in electrodeposition processes.
TY - JOUR
AU - Nikolić, Nebojša D.
AU - Maksimović, Vesna M.
AU - Branković, Goran
PY - 2013
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1362
AB - Electrodeposition of lead from a concentrated nitrate solution was examined by scanning electron microscopy (SEM) and by X-ray diffraction (XRD) analysis of the obtained powder particles. Single crystals of the (111) preferred orientation were formed at a low overpotential by ohmic controlled electrodeposition. Irregular crystals, needle-like and fern-like dendrites, predominantly of the (111) preferred orientation, were formed at high overpotentials (the diffusion control of the electrodeposition). The ratio of Pb crystallites oriented in the (200), (220), (311) and (331) planes increased with increasing electrodeposition overpotential. The correlation between the morphologies and crystallographic structures of the lead deposits was discussed by the consideration of general characteristics of growth layers in electrodeposition processes.
PB - The Royal Society of Chemistry
T2 - RSC Advances
T1 - Morphological and crystallographic characteristics of electrodeposited lead from a concentrated electrolyte
VL - 3
IS - 20
SP - 7466
EP - 7471
DO - 10.1039/c3ra41183d
ER -
@article{
author = "Nikolić, Nebojša D. and Maksimović, Vesna M. and Branković, Goran",
year = "2013",
abstract = "Electrodeposition of lead from a concentrated nitrate solution was examined by scanning electron microscopy (SEM) and by X-ray diffraction (XRD) analysis of the obtained powder particles. Single crystals of the (111) preferred orientation were formed at a low overpotential by ohmic controlled electrodeposition. Irregular crystals, needle-like and fern-like dendrites, predominantly of the (111) preferred orientation, were formed at high overpotentials (the diffusion control of the electrodeposition). The ratio of Pb crystallites oriented in the (200), (220), (311) and (331) planes increased with increasing electrodeposition overpotential. The correlation between the morphologies and crystallographic structures of the lead deposits was discussed by the consideration of general characteristics of growth layers in electrodeposition processes.",
publisher = "The Royal Society of Chemistry",
journal = "RSC Advances",
title = "Morphological and crystallographic characteristics of electrodeposited lead from a concentrated electrolyte",
volume = "3",
number = "20",
pages = "7466-7471",
doi = "10.1039/c3ra41183d"
}
Nikolić, N. D., Maksimović, V. M.,& Branković, G.. (2013). Morphological and crystallographic characteristics of electrodeposited lead from a concentrated electrolyte. in RSC Advances
The Royal Society of Chemistry., 3(20), 7466-7471.
https://doi.org/10.1039/c3ra41183d
Nikolić ND, Maksimović VM, Branković G. Morphological and crystallographic characteristics of electrodeposited lead from a concentrated electrolyte. in RSC Advances. 2013;3(20):7466-7471.
doi:10.1039/c3ra41183d .
Nikolić, Nebojša D., Maksimović, Vesna M., Branković, Goran, "Morphological and crystallographic characteristics of electrodeposited lead from a concentrated electrolyte" in RSC Advances, 3, no. 20 (2013):7466-7471,
https://doi.org/10.1039/c3ra41183d . .
