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dc.creatorAbramović, Biljana F.
dc.creatorBanic, Nemanja D.
dc.creatorKrstić, Jugoslav
dc.date.accessioned2019-01-30T17:37:57Z
dc.date.available2019-01-30T17:37:57Z
dc.date.issued2013
dc.identifier.issn0888-5885
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1355
dc.description.abstractThe possibility of the use of the laminar falling film slurry type photoreactor was examined in conjunction with ZnO as a photocatalyst for the removal of thiacloprid (TCL) from Calypso 480-SC commercial formulation by UV radiation. The degradation kinetics were monitored by HPLC DAD, while the disappearance of the nitrile group, i.e. TCL and intermediates containing this group, was followed by FTIR The study of TCL removal under different operating conditions indicated that 2 g/L of ZnO was an optimal catalyst loading, and the optimal pH was 6.8. In the investigated range of initial concentrations of TCL (0.05-0.38 mM), the photocatalytic degradation in the first stage of the reaction followed approximately a pseudo-first-order kinetics. The increase of LTV-light intensity resulted in a linear increase in the rate of TCL degradation. The figure-of-merit electrical energy per order was employed to estimate the electrical energy consumption. Because the efficiency of TCL photodegradation in the natural thermal water was about two times lower than in distilled water, the investigation encompassed the influence of the thermal water components, i.e. different inorganic ions and humic acid, on the rate of TCL degradation.en
dc.publisherAmer Chemical Soc, Washington
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172042/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS//
dc.rightsrestrictedAccess
dc.sourceIndustrial and Engineering Chemistry Research
dc.titleDegradation of Thiacloprid by ZnO in a Laminar Falling Film Slurry Photocatalytic Reactoren
dc.typearticle
dc.rights.licenseARR
dcterms.abstractБаниц, Немања Д.; Aбрамовић, Биљана Ф.; Крстић, Југослав;
dc.citation.volume52
dc.citation.issue14
dc.citation.spage5040
dc.citation.epage5047
dc.citation.other52(14): 5040-5047
dc.citation.rankM21
dc.identifier.doi10.1021/ie400194m
dc.identifier.rcubConv_2956
dc.identifier.scopus2-s2.0-84876150818
dc.identifier.wos000317548900010
dc.type.versionpublishedVersion


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