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Synthesis, Electrochemistry, and Hierarchical Self-Organization of Fulleropyrrolidine-Phthalimide Dyads

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2013
Authors
Mitrović, Aleksandra
Todorović, Nina
Zekic, Andrijana
Stanković, Dalibor
Milić, Dragana
Maslak, Veselin
Article (Published version)
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Abstract
A series of novel fulleropyrrolidine-phthalimide dyads was synthesized and their electrochemical and self-assembly properties were investigated. Efficient synthesis of acceptor-acceptor dyads was performed under microwave irradiation. Fine-tuning of the second redox potentials in the dyads was achieved by varying the length of the aliphatic spacer (C-2 to C-12) between the fulleropyrrolidine and phthalimide moieties. Shape-shifting and supramolecular polymorphism were observed for these compounds during self-assembly.
Keywords:
Electrochemistry / Cyclic voltammetry / Fullerenes / Microwave chemistry / Dyads / Polymorphism
Source:
European Journal of Organic Chemistry, 2013, 11, 2188-2193
Publisher:
  • Wiley-V C H Verlag Gmbh, Weinheim
Projects:
  • Design, synthesis and investigations of fullerene based nanomolecular machines (RS-172002)

DOI: 10.1002/ejoc.201201631

ISSN: 1434-193X

WoS: 000319398600009

Scopus: 2-s2.0-84887621810
[ Google Scholar ]
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/1345
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