Synergic adsorption of Pb2+ and reactive dye-RB5 on two series of organomodified bentonites
Samo za registrovane korisnike
2013
Autori
Jović-Jovičić, NatašaMilutinović Nikolić, Aleksandra
Žunić, Marija
Mojović, Zorica
Banković, Predrag
Gržetić, Ivan
Jovanović, Dušan M.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Two series of organobentonites (OBs) were synthesized from Na+-exchanged bentonite clay from Bogovina, Serbia. In the first series the starting material was modified using hexadecyltrimethylammonium (HDTMA(+)) ion in the amounts corresponding to 0.2, 0.5, 1.0 and 2.0 of the CEC value. The second series was obtained using quaternary alkyl ammonium cations (QAACs) with different alkyl chain lengths: hexadecyltrimethylammonium (HDTMA(+)), dodecyltrimethylammonium (DDTMA(+)) and tetramethylammonium (TMA(+)) ions. The synthesized OBs were characterized. The adsorption of anionic reactive dye Reactive Black 5 (RB5) and Pb2+ from single component solutions and their hi-component solution was investigated for both series of OBs. The adsorptive properties of the OBs were correlated to the amount and type of incorporated QAACs. The correlation was tested using different mathematical models and best fits were found. Experimental results showed that simultaneous adsorption of RB5 and Pb2+ exhibite...d synergic effect. The adsorption capacity for both RB5 and Pb2+ was higher in their hi-component solution than in single-component solutions. These results indicate the creation of new adsorption sites during the simultaneous adsorption.
Ključne reči:
Reactive dye / Simultaneous adsorption / Lead / Intraparticle diffusion / Multifunctional adsorbentIzvor:
Journal of Contaminant Hydrology, 2013, 150, 1-11Izdavač:
- Elsevier
Finansiranje / projekti:
- Nanostrukturni funkcionalni i kompozitni materijali u katalitičkim i sorpcionim procesima (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- Geohemijska ispitivanja sedimentnih stena - fosilna goriva i zagađivači životne sredine (RS-MESTD-Basic Research (BR or ON)-176006)
DOI: 10.1016/j.jconhyd.2013.03.004
ISSN: 0169-7722
PubMed: 23624568
WoS: 000320088700001
Scopus: 2-s2.0-84876813470
Institucija/grupa
IHTMTY - JOUR AU - Jović-Jovičić, Nataša AU - Milutinović Nikolić, Aleksandra AU - Žunić, Marija AU - Mojović, Zorica AU - Banković, Predrag AU - Gržetić, Ivan AU - Jovanović, Dušan M. PY - 2013 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1337 AB - Two series of organobentonites (OBs) were synthesized from Na+-exchanged bentonite clay from Bogovina, Serbia. In the first series the starting material was modified using hexadecyltrimethylammonium (HDTMA(+)) ion in the amounts corresponding to 0.2, 0.5, 1.0 and 2.0 of the CEC value. The second series was obtained using quaternary alkyl ammonium cations (QAACs) with different alkyl chain lengths: hexadecyltrimethylammonium (HDTMA(+)), dodecyltrimethylammonium (DDTMA(+)) and tetramethylammonium (TMA(+)) ions. The synthesized OBs were characterized. The adsorption of anionic reactive dye Reactive Black 5 (RB5) and Pb2+ from single component solutions and their hi-component solution was investigated for both series of OBs. The adsorptive properties of the OBs were correlated to the amount and type of incorporated QAACs. The correlation was tested using different mathematical models and best fits were found. Experimental results showed that simultaneous adsorption of RB5 and Pb2+ exhibited synergic effect. The adsorption capacity for both RB5 and Pb2+ was higher in their hi-component solution than in single-component solutions. These results indicate the creation of new adsorption sites during the simultaneous adsorption. PB - Elsevier T2 - Journal of Contaminant Hydrology T1 - Synergic adsorption of Pb2+ and reactive dye-RB5 on two series of organomodified bentonites VL - 150 SP - 1 EP - 11 DO - 10.1016/j.jconhyd.2013.03.004 ER -
@article{ author = "Jović-Jovičić, Nataša and Milutinović Nikolić, Aleksandra and Žunić, Marija and Mojović, Zorica and Banković, Predrag and Gržetić, Ivan and Jovanović, Dušan M.", year = "2013", abstract = "Two series of organobentonites (OBs) were synthesized from Na+-exchanged bentonite clay from Bogovina, Serbia. In the first series the starting material was modified using hexadecyltrimethylammonium (HDTMA(+)) ion in the amounts corresponding to 0.2, 0.5, 1.0 and 2.0 of the CEC value. The second series was obtained using quaternary alkyl ammonium cations (QAACs) with different alkyl chain lengths: hexadecyltrimethylammonium (HDTMA(+)), dodecyltrimethylammonium (DDTMA(+)) and tetramethylammonium (TMA(+)) ions. The synthesized OBs were characterized. The adsorption of anionic reactive dye Reactive Black 5 (RB5) and Pb2+ from single component solutions and their hi-component solution was investigated for both series of OBs. The adsorptive properties of the OBs were correlated to the amount and type of incorporated QAACs. The correlation was tested using different mathematical models and best fits were found. Experimental results showed that simultaneous adsorption of RB5 and Pb2+ exhibited synergic effect. The adsorption capacity for both RB5 and Pb2+ was higher in their hi-component solution than in single-component solutions. These results indicate the creation of new adsorption sites during the simultaneous adsorption.", publisher = "Elsevier", journal = "Journal of Contaminant Hydrology", title = "Synergic adsorption of Pb2+ and reactive dye-RB5 on two series of organomodified bentonites", volume = "150", pages = "1-11", doi = "10.1016/j.jconhyd.2013.03.004" }
Jović-Jovičić, N., Milutinović Nikolić, A., Žunić, M., Mojović, Z., Banković, P., Gržetić, I.,& Jovanović, D. M.. (2013). Synergic adsorption of Pb2+ and reactive dye-RB5 on two series of organomodified bentonites. in Journal of Contaminant Hydrology Elsevier., 150, 1-11. https://doi.org/10.1016/j.jconhyd.2013.03.004
Jović-Jovičić N, Milutinović Nikolić A, Žunić M, Mojović Z, Banković P, Gržetić I, Jovanović DM. Synergic adsorption of Pb2+ and reactive dye-RB5 on two series of organomodified bentonites. in Journal of Contaminant Hydrology. 2013;150:1-11. doi:10.1016/j.jconhyd.2013.03.004 .
Jović-Jovičić, Nataša, Milutinović Nikolić, Aleksandra, Žunić, Marija, Mojović, Zorica, Banković, Predrag, Gržetić, Ivan, Jovanović, Dušan M., "Synergic adsorption of Pb2+ and reactive dye-RB5 on two series of organomodified bentonites" in Journal of Contaminant Hydrology, 150 (2013):1-11, https://doi.org/10.1016/j.jconhyd.2013.03.004 . .