Pronounced catalysis of hydrogen evolution reaction (HER) by rhodium nanoislands spontaneously deposited on Au(111) has been observed. Different Rh/Au(111) nanostructures were characterized ex situ by both height and phase imaging AFM. The most pronounced catalytic activity for HER in 0.5 M H2SO4 was obtained for 50% Rh coverage. This is ascribed to the suitable size of Rh nanoislands and to the electronic modification of Rh deposit by Au(111) substrate.
TY - JOUR
AU - Smiljanić, Milutin
AU - Srejić, Irina
AU - Grgur, Branimir N.
AU - Rakočević, Zlatko Lj.
AU - Štrbac, Svetlana
PY - 2013
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/1287
AB - Pronounced catalysis of hydrogen evolution reaction (HER) by rhodium nanoislands spontaneously deposited on Au(111) has been observed. Different Rh/Au(111) nanostructures were characterized ex situ by both height and phase imaging AFM. The most pronounced catalytic activity for HER in 0.5 M H2SO4 was obtained for 50% Rh coverage. This is ascribed to the suitable size of Rh nanoislands and to the electronic modification of Rh deposit by Au(111) substrate.
PB - Elsevier Science Inc, New York
T2 - Electrochemistry Communications
T1 - Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands
VL - 28
SP - 37
EP - 39
DO - 10.1016/j.elecom.2012.12.009
ER -
@article{
author = "Smiljanić, Milutin and Srejić, Irina and Grgur, Branimir N. and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2013",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/1287",
abstract = "Pronounced catalysis of hydrogen evolution reaction (HER) by rhodium nanoislands spontaneously deposited on Au(111) has been observed. Different Rh/Au(111) nanostructures were characterized ex situ by both height and phase imaging AFM. The most pronounced catalytic activity for HER in 0.5 M H2SO4 was obtained for 50% Rh coverage. This is ascribed to the suitable size of Rh nanoislands and to the electronic modification of Rh deposit by Au(111) substrate.",
publisher = "Elsevier Science Inc, New York",
journal = "Electrochemistry Communications",
title = "Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands",
volume = "28",
pages = "37-39",
doi = "10.1016/j.elecom.2012.12.009"
}
Smiljanić, M., Srejić, I., Grgur, B. N., Rakočević, Z. Lj.,& Štrbac, S. (2013). Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands.
Electrochemistry Communications
Elsevier Science Inc, New York., 28, 37-39.
https://doi.org/10.1016/j.elecom.2012.12.009
Smiljanić M, Srejić I, Grgur BN, Rakočević ZL, Štrbac S. Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands. Electrochemistry Communications. 2013;28:37-39
