Phase diagram of the Al-Cu-Sb ternary system was investigated experimentally by DTA and SEM-EDS methods and theoretically by CALPHAD method. The liquidus projection, invariant equilibria, three vertical sections: Sb-Al0.5Cu0.5, Al-Cu0.5Sb0.5 and Cu-Al0.5Sb0.5 as well as isothermal sections at 400 degrees C and 200 degrees C were predicted using COST MP0602 thermodynamic database. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Experimentally obtained phase transition temperatures were compared with the results of thermodynamic calculation. Predicted isothermal sections at 400 degrees C and 200 degrees C were compared with the results of the SEM-EDS analysis from this work. In both cases, a good agreement between theoretical calculations and experimental results was obtained.
TY - JOUR
AU - Minić, Duško
AU - Premović, Milena
AU - Ćosović, Vladan
AU - Manasijević, Dragan
AU - Živković, Dragana
AU - Kostov, Ana
AU - Talijan, Nadežda M.
PY - 2013
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/1275
AB - Phase diagram of the Al-Cu-Sb ternary system was investigated experimentally by DTA and SEM-EDS methods and theoretically by CALPHAD method. The liquidus projection, invariant equilibria, three vertical sections: Sb-Al0.5Cu0.5, Al-Cu0.5Sb0.5 and Cu-Al0.5Sb0.5 as well as isothermal sections at 400 degrees C and 200 degrees C were predicted using COST MP0602 thermodynamic database. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Experimentally obtained phase transition temperatures were compared with the results of thermodynamic calculation. Predicted isothermal sections at 400 degrees C and 200 degrees C were compared with the results of the SEM-EDS analysis from this work. In both cases, a good agreement between theoretical calculations and experimental results was obtained.
PB - Elsevier
T2 - Journal of Alloys and Compounds
T1 - Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram
VL - 555
SP - 347
EP - 356
DO - 10.1016/j.jallcom.2012.12.059
ER -
@article{
author = "Minić, Duško and Premović, Milena and Ćosović, Vladan and Manasijević, Dragan and Živković, Dragana and Kostov, Ana and Talijan, Nadežda M.",
year = "2013",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/1275",
abstract = "Phase diagram of the Al-Cu-Sb ternary system was investigated experimentally by DTA and SEM-EDS methods and theoretically by CALPHAD method. The liquidus projection, invariant equilibria, three vertical sections: Sb-Al0.5Cu0.5, Al-Cu0.5Sb0.5 and Cu-Al0.5Sb0.5 as well as isothermal sections at 400 degrees C and 200 degrees C were predicted using COST MP0602 thermodynamic database. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Experimentally obtained phase transition temperatures were compared with the results of thermodynamic calculation. Predicted isothermal sections at 400 degrees C and 200 degrees C were compared with the results of the SEM-EDS analysis from this work. In both cases, a good agreement between theoretical calculations and experimental results was obtained.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram",
volume = "555",
pages = "347-356",
doi = "10.1016/j.jallcom.2012.12.059"
}
Minić D, Premović M, Ćosović V, Manasijević D, Živković D, Kostov A, Talijan NM. Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram. Journal of Alloys and Compounds. 2013;555:347-356
Minić, D., Premović, M., Ćosović, V., Manasijević, D., Živković, D., Kostov, A.,& Talijan, N. M. (2013). Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram.
Journal of Alloys and CompoundsElsevier., 555, 347-356.
https://doi.org/10.1016/j.jallcom.2012.12.059
Minić Duško, Premović Milena, Ćosović Vladan, Manasijević Dragan, Živković Dragana, Kostov Ana, Talijan Nadežda M., "Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram" 555 (2013):347-356,
https://doi.org/10.1016/j.jallcom.2012.12.059 .
