CER - Central Repository
Institute of Chemistry, Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   CER
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
  •   CER
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Monolayer gas adsorption in plasmonic sensors: Comparative analysis of kinetic models

Authorized Users Only
2013
Authors
Jakšić, Olga
Čupić, Željko
Jakšić, Zoran
Randjelović, Danijela
Kolar-Anić, Ljiljana
Article (Published version)
Metadata
Show full item record
Abstract
The analysis of adsorption kinetics is given, assuming no dissociative adsorption takes place and no multiple binding sites exist. The phenomenological nonlinear model and the simple linear model are considered from the point of view of surface plasmon resonance (SPR) chemical sensors. A simple method for analytical calculation of the necessary rate constants is proposed. A comparative analysis of the described models is performed. Two conditions that affect the validity of the linear model are found. First one, referring to the ratio between the overall number of particles and the number of binding sites, and the second one, that guarantees the validity of linear model in much broader spectrum of practical situations, referring to the ratio of rate constants. A method for avoiding the accumulation of numerical errors in calculus is also proposed. The presented approach is general and can be used in various applications, including other types of chemical sensors, membranes for filterin...g, different catalytic systems, resonant micro or nano-electro-mechanical structures.

Keywords:
adsorption / desorption / Langmuir kinetics / plasmonic sensors
Source:
Russian Journal of Physical Chemistry A, 2013, 87, 13, 2134-2139
Publisher:
  • Maik Nauka/Interperiodica/Springer, New York
Funding / projects:
  • Micro- Nanosystems and Sensors for Electric Power and Process Industry and Environmental Protection (RS-32008)
  • Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
  • Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions (RS-172015)

DOI: 10.1134/S0036024413130128

ISSN: 0036-0244

WoS: 000326718200004

Scopus: 2-s2.0-84888145615
[ Google Scholar ]
7
7
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/1258
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Jakšić, Olga
AU  - Čupić, Željko
AU  - Jakšić, Zoran
AU  - Randjelović, Danijela
AU  - Kolar-Anić, Ljiljana
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1258
AB  - The analysis of adsorption kinetics is given, assuming no dissociative adsorption takes place and no multiple binding sites exist. The phenomenological nonlinear model and the simple linear model are considered from the point of view of surface plasmon resonance (SPR) chemical sensors. A simple method for analytical calculation of the necessary rate constants is proposed. A comparative analysis of the described models is performed. Two conditions that affect the validity of the linear model are found. First one, referring to the ratio between the overall number of particles and the number of binding sites, and the second one, that guarantees the validity of linear model in much broader spectrum of practical situations, referring to the ratio of rate constants. A method for avoiding the accumulation of numerical errors in calculus is also proposed. The presented approach is general and can be used in various applications, including other types of chemical sensors, membranes for filtering, different catalytic systems, resonant micro or nano-electro-mechanical structures.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Monolayer gas adsorption in plasmonic sensors: Comparative analysis of kinetic models
VL  - 87
IS  - 13
SP  - 2134
EP  - 2139
DO  - 10.1134/S0036024413130128
ER  - 
@article{
author = "Jakšić, Olga and Čupić, Željko and Jakšić, Zoran and Randjelović, Danijela and Kolar-Anić, Ljiljana",
year = "2013",
abstract = "The analysis of adsorption kinetics is given, assuming no dissociative adsorption takes place and no multiple binding sites exist. The phenomenological nonlinear model and the simple linear model are considered from the point of view of surface plasmon resonance (SPR) chemical sensors. A simple method for analytical calculation of the necessary rate constants is proposed. A comparative analysis of the described models is performed. Two conditions that affect the validity of the linear model are found. First one, referring to the ratio between the overall number of particles and the number of binding sites, and the second one, that guarantees the validity of linear model in much broader spectrum of practical situations, referring to the ratio of rate constants. A method for avoiding the accumulation of numerical errors in calculus is also proposed. The presented approach is general and can be used in various applications, including other types of chemical sensors, membranes for filtering, different catalytic systems, resonant micro or nano-electro-mechanical structures.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Monolayer gas adsorption in plasmonic sensors: Comparative analysis of kinetic models",
volume = "87",
number = "13",
pages = "2134-2139",
doi = "10.1134/S0036024413130128"
}
Jakšić, O., Čupić, Ž., Jakšić, Z., Randjelović, D.,& Kolar-Anić, L.. (2013). Monolayer gas adsorption in plasmonic sensors: Comparative analysis of kinetic models. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 87(13), 2134-2139.
https://doi.org/10.1134/S0036024413130128
Jakšić O, Čupić Ž, Jakšić Z, Randjelović D, Kolar-Anić L. Monolayer gas adsorption in plasmonic sensors: Comparative analysis of kinetic models. in Russian Journal of Physical Chemistry A. 2013;87(13):2134-2139.
doi:10.1134/S0036024413130128 .
Jakšić, Olga, Čupić, Željko, Jakšić, Zoran, Randjelović, Danijela, Kolar-Anić, Ljiljana, "Monolayer gas adsorption in plasmonic sensors: Comparative analysis of kinetic models" in Russian Journal of Physical Chemistry A, 87, no. 13 (2013):2134-2139,
https://doi.org/10.1134/S0036024413130128 . .

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

re3dataOpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

re3dataOpenAIRERCUB