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dc.creatorMarković, Svetlana
dc.creatorMarkovic, Violeta
dc.creatorJoksovic, Milan D.
dc.creatorTodorović, Nina
dc.creatorJoksovic, Ljubinka
dc.creatorDivjakovic, Vladimir
dc.creatorTrifunović, Snežana
dc.date.accessioned2019-01-30T17:35:03Z
dc.date.available2019-01-30T17:35:03Z
dc.date.issued2013
dc.identifier.issn0103-5053
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/1222
dc.description.abstractReductive debromination of endo-(+)-3-bromocamphor with different primary amines followed by imine formation was investigated. This reaction requires simple experimental procedure without any organic solvent, metal or conventional reducing agent. A strong influence of amine polarity on the efficacy of debromination process was observed, and ethanolamine and ethylene diamine having sufficiently high boiling points can debrominate 3-bromocamphor giving corresponding camphanimines in good isolated yields. The mechanisms of debromination of 3-bromocamphor with ethanolamine and n-hexylamine were investigated at the B3LYP/6-311+G(d,p) level of theory. The radical mechanism was revealed, and it was shown that the reaction with more polar ethanolamine is energetically more favorable.en
dc.publisherSoc Brasileira Quimica, Sao Paulo
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172016/RS//
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.sourceJournal of the Brazilian Chemical Society
dc.subject3-bromocamphoren
dc.subjectprimary aminesen
dc.subjectreductive debrominationen
dc.subjectreaction mechanismen
dc.subjectDFTen
dc.titleDebromination of endo-(+)-3-Bromocamphor with Primary Aminesen
dc.typearticle
dc.rights.licenseBY
dcterms.abstractТодоровић, Нина; Марковиц, Виолета; Трифуновиц, Снезана; Јоксовиц, Љубинка; Марковић, Светлана; Дивјаковиц, Владимир; Јоксовиц, Милан Д.;
dc.citation.volume24
dc.citation.issue7
dc.citation.spage1099
dc.citation.other24(7): 1099
dc.citation.rankM22
dc.identifier.doi10.5935/0103-5053.20130144
dc.identifier.fulltexthttps://cer.ihtm.bg.ac.rs//bitstream/id/7737/1220.pdf
dc.identifier.scopus2-s2.0-84880656725
dc.identifier.wos000322727100003
dc.type.versionpublishedVersion


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Приказ основних података о документу