Show simple item record

dc.creatorMarjanovic, Jasna
dc.creatorDivjakovic, Vladimir
dc.creatorMatović, Radomir
dc.creatorFerjančić, Zorana
dc.creatorSaičić, Radomir N.
dc.date.accessioned2019-01-30T17:34:56Z
dc.date.available2019-01-30T17:34:56Z
dc.date.issued2013
dc.identifier.issn1434-193X
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/1215
dc.description.abstractThe stereodivergent synthesis of two hyacinthacine analogues, which relies on an organocatalyzed aldol addition, is described. The aldol addition of dioxanone to an -N-carbobenzyloxy-substituted chiral aldehyde, promoted by both (R)- and (S)-proline, proceeds in reasonable yields with acceptable diastereomeric ratios. The success of the reaction may be due to the use of an acyclic aldehyde acceptor, which allows reagent control of the stereochemical outcome of the key aldolization step in both the matched and mismatched cases.en
dc.publisherWiley-V C H Verlag Gmbh, Weinheim
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172027/RS//
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/256716/EU//
dc.relationMunicipality of Stari Grad
dc.rightsrestrictedAccess
dc.sourceEuropean Journal of Organic Chemistry
dc.subjectAsymmetric synthesisen
dc.subjectAzasugarsen
dc.subjectNatural productsen
dc.subjectOrganocatalysisen
dc.subjectAldol reactionsen
dc.titleDouble Asymmetric Induction in Organocatalyzed Aldol Reactions: Total Synthesis of (+)-2-epi-Hyacinthacine A(2) and (-)-3-epi-Hyacinthacine A(1)en
dc.typearticle
dc.rights.licenseARR
dcterms.abstractМарјановиц, Јасна; Дивјаковиц, Владимир; Ферјанциц, Зорана; Саициц, Радомир Н.; Матовић, Радомир;
dc.citation.volume2013
dc.citation.issue25
dc.citation.spage5555
dc.citation.epage5560
dc.citation.other2013(25): 5555-5560
dc.citation.rankM21
dc.identifier.doi10.1002/ejoc.201300716
dc.identifier.scopus2-s2.0-84882875459
dc.identifier.wos000323319500004
dc.type.versionpublishedVersion


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record