Influence of the chemical structure of poly(urea-urethane-siloxane)s on their morphological, surface and thermal properties
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2013
Authors
Balaban, MilicaAntić, Vesna
Pergal, Marija
Gođevac, Dejan
Francolini, Iolanda
Martinelli, Andrea
Rogan, Jelena R.
Đonlagić, Jasna
Article (Published version)
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Show full item recordAbstract
Segmented poly(urethane-urea-siloxane)s (PUUS) were synthesized using 4,4'-methylenediphenyl diisocyanate (MDI) and ethylene diamine (ED) as the hard segment components and hydroxypropyl-terminated poly(dimethylsiloxane) (PDMS) as the soft segment component, where the hard segment content ranged from 38 to 65 wt%. Segmented PUUSs were prepared by a two-step polymerization procedure in tetrahydrofuran/N-methylpyrrolidone (THF/NMP) mixture with a large proportion of polar solvent. The structure, composition and hard segment length were determined by C-13 NMR and two-dimensional correlation spectroscopy. Thermal, mechanical, small-angle X-ray scattering and hydrogen bonding analyses indicated the formation of the microphase-separated copolymers with high tensile strength. Globular superstructures observed in the copolymer films by scanning electron microscopy (SEM) and atomic force microscopy (AFM) were probably arisen from the microstructural organization of the MDI-ED segments, dependin...g on their content and length. The PUUS copolymers showed high water resistance and became more hydrophobic with increasing weight fraction of PDMS.
Keywords:
Segmented polyurethane-ureas / Hydroxypropyl-terminated PDMS / Quantitative C-13 NMR spectroscopy / Thermal properties / MorphologySource:
Polymer Bulletin, 2013, 70, 9, 2493-2518Publisher:
- Springer Verlag
Funding / projects:
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)
DOI: 10.1007/s00289-013-0968-2
ISSN: 0170-0839
WoS: 000322156300001
Scopus: 2-s2.0-84881188143
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IHTMTY - JOUR AU - Balaban, Milica AU - Antić, Vesna AU - Pergal, Marija AU - Gođevac, Dejan AU - Francolini, Iolanda AU - Martinelli, Andrea AU - Rogan, Jelena R. AU - Đonlagić, Jasna PY - 2013 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1204 AB - Segmented poly(urethane-urea-siloxane)s (PUUS) were synthesized using 4,4'-methylenediphenyl diisocyanate (MDI) and ethylene diamine (ED) as the hard segment components and hydroxypropyl-terminated poly(dimethylsiloxane) (PDMS) as the soft segment component, where the hard segment content ranged from 38 to 65 wt%. Segmented PUUSs were prepared by a two-step polymerization procedure in tetrahydrofuran/N-methylpyrrolidone (THF/NMP) mixture with a large proportion of polar solvent. The structure, composition and hard segment length were determined by C-13 NMR and two-dimensional correlation spectroscopy. Thermal, mechanical, small-angle X-ray scattering and hydrogen bonding analyses indicated the formation of the microphase-separated copolymers with high tensile strength. Globular superstructures observed in the copolymer films by scanning electron microscopy (SEM) and atomic force microscopy (AFM) were probably arisen from the microstructural organization of the MDI-ED segments, depending on their content and length. The PUUS copolymers showed high water resistance and became more hydrophobic with increasing weight fraction of PDMS. PB - Springer Verlag T2 - Polymer Bulletin T1 - Influence of the chemical structure of poly(urea-urethane-siloxane)s on their morphological, surface and thermal properties VL - 70 IS - 9 SP - 2493 EP - 2518 DO - 10.1007/s00289-013-0968-2 ER -
@article{ author = "Balaban, Milica and Antić, Vesna and Pergal, Marija and Gođevac, Dejan and Francolini, Iolanda and Martinelli, Andrea and Rogan, Jelena R. and Đonlagić, Jasna", year = "2013", abstract = "Segmented poly(urethane-urea-siloxane)s (PUUS) were synthesized using 4,4'-methylenediphenyl diisocyanate (MDI) and ethylene diamine (ED) as the hard segment components and hydroxypropyl-terminated poly(dimethylsiloxane) (PDMS) as the soft segment component, where the hard segment content ranged from 38 to 65 wt%. Segmented PUUSs were prepared by a two-step polymerization procedure in tetrahydrofuran/N-methylpyrrolidone (THF/NMP) mixture with a large proportion of polar solvent. The structure, composition and hard segment length were determined by C-13 NMR and two-dimensional correlation spectroscopy. Thermal, mechanical, small-angle X-ray scattering and hydrogen bonding analyses indicated the formation of the microphase-separated copolymers with high tensile strength. Globular superstructures observed in the copolymer films by scanning electron microscopy (SEM) and atomic force microscopy (AFM) were probably arisen from the microstructural organization of the MDI-ED segments, depending on their content and length. The PUUS copolymers showed high water resistance and became more hydrophobic with increasing weight fraction of PDMS.", publisher = "Springer Verlag", journal = "Polymer Bulletin", title = "Influence of the chemical structure of poly(urea-urethane-siloxane)s on their morphological, surface and thermal properties", volume = "70", number = "9", pages = "2493-2518", doi = "10.1007/s00289-013-0968-2" }
Balaban, M., Antić, V., Pergal, M., Gođevac, D., Francolini, I., Martinelli, A., Rogan, J. R.,& Đonlagić, J.. (2013). Influence of the chemical structure of poly(urea-urethane-siloxane)s on their morphological, surface and thermal properties. in Polymer Bulletin Springer Verlag., 70(9), 2493-2518. https://doi.org/10.1007/s00289-013-0968-2
Balaban M, Antić V, Pergal M, Gođevac D, Francolini I, Martinelli A, Rogan JR, Đonlagić J. Influence of the chemical structure of poly(urea-urethane-siloxane)s on their morphological, surface and thermal properties. in Polymer Bulletin. 2013;70(9):2493-2518. doi:10.1007/s00289-013-0968-2 .
Balaban, Milica, Antić, Vesna, Pergal, Marija, Gođevac, Dejan, Francolini, Iolanda, Martinelli, Andrea, Rogan, Jelena R., Đonlagić, Jasna, "Influence of the chemical structure of poly(urea-urethane-siloxane)s on their morphological, surface and thermal properties" in Polymer Bulletin, 70, no. 9 (2013):2493-2518, https://doi.org/10.1007/s00289-013-0968-2 . .