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Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud. Estimation of density distribution function of the apparent activation energy
Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud were carried out using thermogravimetry (TG), derivative thermogravimetry (DTG), differential scanning calorimetry (DSC), differential thermal analysis (DTA) and Fourier transform infrared spectroscopy (FTIR). It was found that the investigated decomposition was a complex heterogeneous process, which included two main decomposition stages and one sub-stage. The overall decomposition process consisted of the series of parallel and competitive reactions, which originated from the decomposition of various chemical species and solid-state transformations. This behavior was confirmed by the appearance of different forms of density distribution functions of apparent activation energy values. Furthermore, the conversion range of 0.10 LT = alpha LT = 0.30, with a constant value of the apparent activation energy (146.4 kJ mol(-1)) for the second stage of the overall process, belongs to cal...cite decomposition, which takes place through a two-dimensional diffusion mechanism.
Keywords:
Bauxite red mud / Decomposition / Kinetics / Apparent activation energy / Density distribution function
Source:
International Journal of Mineral Processing, 2013, 123, 46-59
TY - JOUR
AU - Jankovic, Bojan
AU - Smiciklas, Ivana
AU - Stajić-Trošić, Jasna
AU - Antonovic, Dusan
PY - 2013
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1178
AB - Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud were carried out using thermogravimetry (TG), derivative thermogravimetry (DTG), differential scanning calorimetry (DSC), differential thermal analysis (DTA) and Fourier transform infrared spectroscopy (FTIR). It was found that the investigated decomposition was a complex heterogeneous process, which included two main decomposition stages and one sub-stage. The overall decomposition process consisted of the series of parallel and competitive reactions, which originated from the decomposition of various chemical species and solid-state transformations. This behavior was confirmed by the appearance of different forms of density distribution functions of apparent activation energy values. Furthermore, the conversion range of 0.10 LT = alpha LT = 0.30, with a constant value of the apparent activation energy (146.4 kJ mol(-1)) for the second stage of the overall process, belongs to calcite decomposition, which takes place through a two-dimensional diffusion mechanism.
PB - Elsevier
T2 - International Journal of Mineral Processing
T1 - Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud. Estimation of density distribution function of the apparent activation energy
VL - 123
SP - 46
EP - 59
DO - 10.1016/j.minpro.2013.05.003
ER -
@article{
author = "Jankovic, Bojan and Smiciklas, Ivana and Stajić-Trošić, Jasna and Antonovic, Dusan",
year = "2013",
abstract = "Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud were carried out using thermogravimetry (TG), derivative thermogravimetry (DTG), differential scanning calorimetry (DSC), differential thermal analysis (DTA) and Fourier transform infrared spectroscopy (FTIR). It was found that the investigated decomposition was a complex heterogeneous process, which included two main decomposition stages and one sub-stage. The overall decomposition process consisted of the series of parallel and competitive reactions, which originated from the decomposition of various chemical species and solid-state transformations. This behavior was confirmed by the appearance of different forms of density distribution functions of apparent activation energy values. Furthermore, the conversion range of 0.10 LT = alpha LT = 0.30, with a constant value of the apparent activation energy (146.4 kJ mol(-1)) for the second stage of the overall process, belongs to calcite decomposition, which takes place through a two-dimensional diffusion mechanism.",
publisher = "Elsevier",
journal = "International Journal of Mineral Processing",
title = "Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud. Estimation of density distribution function of the apparent activation energy",
volume = "123",
pages = "46-59",
doi = "10.1016/j.minpro.2013.05.003"
}
Jankovic, B., Smiciklas, I., Stajić-Trošić, J.,& Antonovic, D.. (2013). Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud. Estimation of density distribution function of the apparent activation energy. in International Journal of Mineral Processing
Elsevier., 123, 46-59.
https://doi.org/10.1016/j.minpro.2013.05.003
Jankovic B, Smiciklas I, Stajić-Trošić J, Antonovic D. Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud. Estimation of density distribution function of the apparent activation energy. in International Journal of Mineral Processing. 2013;123:46-59.
doi:10.1016/j.minpro.2013.05.003 .
Jankovic, Bojan, Smiciklas, Ivana, Stajić-Trošić, Jasna, Antonovic, Dusan, "Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud. Estimation of density distribution function of the apparent activation energy" in International Journal of Mineral Processing, 123 (2013):46-59,
https://doi.org/10.1016/j.minpro.2013.05.003 . .
