The aim of this study is synthesis of copper-sulfate pentahydrate from the waste sulfuric acid solution-mother liquor generated during the regeneration process of copper bleed solution. Copper is removed from the mother liquor solution in the process of the electrolytic treatment using the insoluble lead anodes alloyed with 6 mass pct of antimony on the industrial-scale equipment. As the result of the decopperization process, copper is removed in the form of the cathode sludge and is precipitated at the bottom of the electrolytic cell. By this procedure, the content of copper could be reduced to the 20 mass pct of the initial value. Chemical characterization of the sludge has shown that it contains about 90 mass pct of copper. During the decopperization process, the very strong poison, arsine, can be formed, and the process is in that case terminated. The copper leaching degree of 82 mass pct is obtained using H2SO4 aqueous solution with the oxygen addition during the cathode sludge ch...emical treatment at 80 A degrees C +/- A 5 A degrees C. Obtained copper salt satisfies the requirements of the Serbian Standard for Pesticide, SRPS H.P1. 058. Therefore, the treatment of waste sulfuric acid solutions is of great economic and environmental interest. DOI: 10.1007/s11663-012-9721-8
Source:
Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 2012, 43, 6, 1388-1392
TY - JOUR
AU - Marković, Radmila
AU - Stevanović, Jasmina
AU - Avramović, Ljiljana
AU - Nedeljković, Dragutin
AU - Jugović, Branimir
AU - Stajić-Trošić, Jasna
AU - Gvozdenović, Milica M.
PY - 2012
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/1052
AB - The aim of this study is synthesis of copper-sulfate pentahydrate from the waste sulfuric acid solution-mother liquor generated during the regeneration process of copper bleed solution. Copper is removed from the mother liquor solution in the process of the electrolytic treatment using the insoluble lead anodes alloyed with 6 mass pct of antimony on the industrial-scale equipment. As the result of the decopperization process, copper is removed in the form of the cathode sludge and is precipitated at the bottom of the electrolytic cell. By this procedure, the content of copper could be reduced to the 20 mass pct of the initial value. Chemical characterization of the sludge has shown that it contains about 90 mass pct of copper. During the decopperization process, the very strong poison, arsine, can be formed, and the process is in that case terminated. The copper leaching degree of 82 mass pct is obtained using H2SO4 aqueous solution with the oxygen addition during the cathode sludge chemical treatment at 80 A degrees C +/- A 5 A degrees C. Obtained copper salt satisfies the requirements of the Serbian Standard for Pesticide, SRPS H.P1. 058. Therefore, the treatment of waste sulfuric acid solutions is of great economic and environmental interest. DOI: 10.1007/s11663-012-9721-8
PB - Springer, New York
T2 - Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science
T1 - Copper-Sulfate Pentahydrate as a Product of the Waste Sulfuric Acid Solution Treatment
VL - 43
IS - 6
SP - 1388
EP - 1392
DO - 10.1007/s11663-012-9721-8
ER -
@article{
author = "Marković, Radmila and Stevanović, Jasmina and Avramović, Ljiljana and Nedeljković, Dragutin and Jugović, Branimir and Stajić-Trošić, Jasna and Gvozdenović, Milica M.",
year = "2012",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/1052",
abstract = "The aim of this study is synthesis of copper-sulfate pentahydrate from the waste sulfuric acid solution-mother liquor generated during the regeneration process of copper bleed solution. Copper is removed from the mother liquor solution in the process of the electrolytic treatment using the insoluble lead anodes alloyed with 6 mass pct of antimony on the industrial-scale equipment. As the result of the decopperization process, copper is removed in the form of the cathode sludge and is precipitated at the bottom of the electrolytic cell. By this procedure, the content of copper could be reduced to the 20 mass pct of the initial value. Chemical characterization of the sludge has shown that it contains about 90 mass pct of copper. During the decopperization process, the very strong poison, arsine, can be formed, and the process is in that case terminated. The copper leaching degree of 82 mass pct is obtained using H2SO4 aqueous solution with the oxygen addition during the cathode sludge chemical treatment at 80 A degrees C +/- A 5 A degrees C. Obtained copper salt satisfies the requirements of the Serbian Standard for Pesticide, SRPS H.P1. 058. Therefore, the treatment of waste sulfuric acid solutions is of great economic and environmental interest. DOI: 10.1007/s11663-012-9721-8",
publisher = "Springer, New York",
journal = "Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science",
title = "Copper-Sulfate Pentahydrate as a Product of the Waste Sulfuric Acid Solution Treatment",
volume = "43",
number = "6",
pages = "1388-1392",
doi = "10.1007/s11663-012-9721-8"
}
Marković, R., Stevanović, J., Avramović, L., Nedeljković, D., Jugović, B., Stajić-Trošić, J.,& Gvozdenović, M. M. (2012). Copper-Sulfate Pentahydrate as a Product of the Waste Sulfuric Acid Solution Treatment.
Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science
Springer, New York., 43(6), 1388-1392.
https://doi.org/10.1007/s11663-012-9721-8
Marković R, Stevanović J, Avramović L, Nedeljković D, Jugović B, Stajić-Trošić J, Gvozdenović MM. Copper-Sulfate Pentahydrate as a Product of the Waste Sulfuric Acid Solution Treatment. Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science. 2012;43(6):1388-1392
Marković Radmila, Stevanović Jasmina, Avramović Ljiljana, Nedeljković Dragutin, Jugović Branimir, Stajić-Trošić Jasna, Gvozdenović Milica M., "Copper-Sulfate Pentahydrate as a Product of the Waste Sulfuric Acid Solution Treatment" Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 43, no. 6 (2012):1388-1392,
https://doi.org/10.1007/s11663-012-9721-8 .
