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Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials

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2012
7010686.pdf (686.6Kb)
Authors
Popov, Konstantin I.
Živković, Predrag M.
Nikolić, Nebojša D.
Article (Published version)
Metadata
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Abstract
In this study, electrodeposition of silver from nitrate solution at the high overpotentials was analyzed. Morphologies of silver deposits obtained at the different overpotentials and with the different electrodeposition times were examined using the technique of scanning electron microscopy (SEM). The different disperse morphological forms, such as granules, needle-like and spongy-dendritic ones were formed during silver electrodeposition from this solution. The size of granules decreased and their number increased with the increase of overpotential of electrodeposition. With the increasing overpotential, the induction time for the appearance of spongy-dendritic forms decreased with a tendency to increase their ramification. Mathematic model describing the mechanism of metal electrodeposition at the high overpotentials is proposed and discussed on the basis of the obtained silver surface morphology.
Keywords:
Silver / electrodeposition / granules / spongy-dendritic form / scanning electron microscopy
Source:
International Journal of Electrochemical Science, 2012, 7, 1, 686-696
Publisher:
  • Esg, Belgrade
Funding / projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)

ISSN: 1452-3981

WoS: 000302723700054

Scopus: 2-s2.0-84855462938
[ Google Scholar ]
7
8
Handle
https://hdl.handle.net/21.15107/rcub_cer_1020
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/1020
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Popov, Konstantin I.
AU  - Živković, Predrag M.
AU  - Nikolić, Nebojša D.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1020
AB  - In this study, electrodeposition of silver from nitrate solution at the high overpotentials was analyzed. Morphologies of silver deposits obtained at the different overpotentials and with the different electrodeposition times were examined using the technique of scanning electron microscopy (SEM). The different disperse morphological forms, such as granules, needle-like and spongy-dendritic ones were formed during silver electrodeposition from this solution. The size of granules decreased and their number increased with the increase of overpotential of electrodeposition. With the increasing overpotential, the induction time for the appearance of spongy-dendritic forms decreased with a tendency to increase their ramification. Mathematic model describing the mechanism of metal electrodeposition at the high overpotentials is proposed and discussed on the basis of the obtained silver surface morphology.
PB  - Esg, Belgrade
T2  - International Journal of Electrochemical Science
T1  - Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials
VL  - 7
IS  - 1
SP  - 686
EP  - 696
UR  - https://hdl.handle.net/21.15107/rcub_cer_1020
ER  - 
@article{
author = "Popov, Konstantin I. and Živković, Predrag M. and Nikolić, Nebojša D.",
year = "2012",
abstract = "In this study, electrodeposition of silver from nitrate solution at the high overpotentials was analyzed. Morphologies of silver deposits obtained at the different overpotentials and with the different electrodeposition times were examined using the technique of scanning electron microscopy (SEM). The different disperse morphological forms, such as granules, needle-like and spongy-dendritic ones were formed during silver electrodeposition from this solution. The size of granules decreased and their number increased with the increase of overpotential of electrodeposition. With the increasing overpotential, the induction time for the appearance of spongy-dendritic forms decreased with a tendency to increase their ramification. Mathematic model describing the mechanism of metal electrodeposition at the high overpotentials is proposed and discussed on the basis of the obtained silver surface morphology.",
publisher = "Esg, Belgrade",
journal = "International Journal of Electrochemical Science",
title = "Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials",
volume = "7",
number = "1",
pages = "686-696",
url = "https://hdl.handle.net/21.15107/rcub_cer_1020"
}
Popov, K. I., Živković, P. M.,& Nikolić, N. D.. (2012). Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials. in International Journal of Electrochemical Science
Esg, Belgrade., 7(1), 686-696.
https://hdl.handle.net/21.15107/rcub_cer_1020
Popov KI, Živković PM, Nikolić ND. Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials. in International Journal of Electrochemical Science. 2012;7(1):686-696.
https://hdl.handle.net/21.15107/rcub_cer_1020 .
Popov, Konstantin I., Živković, Predrag M., Nikolić, Nebojša D., "Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials" in International Journal of Electrochemical Science, 7, no. 1 (2012):686-696,
https://hdl.handle.net/21.15107/rcub_cer_1020 .

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