Microporous conducting nitrogen-containing nanostructured carbon with excellent catalytic activity for the electrochemical synthesis of hydrogen peroxide was synthesized by the carbonization of self-assembled polyaniline 3,5-dinitrosalicylate nanorods. Carbonization was carried out by means of gradual heating in a nitrogen atmosphere up to 800 degrees C. Carbonized polyaniline nanorods containing 9.8 wt.% of nitrogen had a conductivity of 0.35 S cm(-1). The electrical characteristics, morphology, textural parameters, elemental composition, molecular structure and crystallinity of novel carbonized nanostructured polyaniline were investigated by conductivity measurements, scanning and transmission electron microscopies, nitrogen adsorption-desorption measurements, elemental microanalysis, XPS, FTIR and Raman spectroscopies, and XRD, respectively. The electrocatalytic activity of carbonized polyaniline nanorods towards oxygen reduction in alkaline conditions has been studied by the voltam...metry with the rotating disk electrode.
TY - JOUR
AU - Janošević, Aleksandra
AU - Pasti, Igor
AU - Gavrilov, Nemanja
AU - Mentus, Slavko
AU - Krstić, Jugoslav
AU - Mitrić, Miodrag
AU - Travas-Sejdic, Jadranka
AU - Ciric-Marjanovic, Gordana
PY - 2012
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1001
AB - Microporous conducting nitrogen-containing nanostructured carbon with excellent catalytic activity for the electrochemical synthesis of hydrogen peroxide was synthesized by the carbonization of self-assembled polyaniline 3,5-dinitrosalicylate nanorods. Carbonization was carried out by means of gradual heating in a nitrogen atmosphere up to 800 degrees C. Carbonized polyaniline nanorods containing 9.8 wt.% of nitrogen had a conductivity of 0.35 S cm(-1). The electrical characteristics, morphology, textural parameters, elemental composition, molecular structure and crystallinity of novel carbonized nanostructured polyaniline were investigated by conductivity measurements, scanning and transmission electron microscopies, nitrogen adsorption-desorption measurements, elemental microanalysis, XPS, FTIR and Raman spectroscopies, and XRD, respectively. The electrocatalytic activity of carbonized polyaniline nanorods towards oxygen reduction in alkaline conditions has been studied by the voltammetry with the rotating disk electrode.
PB - Elsevier
T2 - Microporous and Mesoporous Materials
T1 - Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties
VL - 152
SP - 50
EP - 57
DO - 10.1016/j.micromeso.2011.12.002
ER -
@article{
author = "Janošević, Aleksandra and Pasti, Igor and Gavrilov, Nemanja and Mentus, Slavko and Krstić, Jugoslav and Mitrić, Miodrag and Travas-Sejdic, Jadranka and Ciric-Marjanovic, Gordana",
year = "2012",
abstract = "Microporous conducting nitrogen-containing nanostructured carbon with excellent catalytic activity for the electrochemical synthesis of hydrogen peroxide was synthesized by the carbonization of self-assembled polyaniline 3,5-dinitrosalicylate nanorods. Carbonization was carried out by means of gradual heating in a nitrogen atmosphere up to 800 degrees C. Carbonized polyaniline nanorods containing 9.8 wt.% of nitrogen had a conductivity of 0.35 S cm(-1). The electrical characteristics, morphology, textural parameters, elemental composition, molecular structure and crystallinity of novel carbonized nanostructured polyaniline were investigated by conductivity measurements, scanning and transmission electron microscopies, nitrogen adsorption-desorption measurements, elemental microanalysis, XPS, FTIR and Raman spectroscopies, and XRD, respectively. The electrocatalytic activity of carbonized polyaniline nanorods towards oxygen reduction in alkaline conditions has been studied by the voltammetry with the rotating disk electrode.",
publisher = "Elsevier",
journal = "Microporous and Mesoporous Materials",
title = "Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties",
volume = "152",
pages = "50-57",
doi = "10.1016/j.micromeso.2011.12.002"
}
Janošević, A., Pasti, I., Gavrilov, N., Mentus, S., Krstić, J., Mitrić, M., Travas-Sejdic, J.,& Ciric-Marjanovic, G.. (2012). Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties. in Microporous and Mesoporous Materials
Elsevier., 152, 50-57.
https://doi.org/10.1016/j.micromeso.2011.12.002
Janošević A, Pasti I, Gavrilov N, Mentus S, Krstić J, Mitrić M, Travas-Sejdic J, Ciric-Marjanovic G. Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties. in Microporous and Mesoporous Materials. 2012;152:50-57.
doi:10.1016/j.micromeso.2011.12.002 .
