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Electrocatalysis by foreign metal monolayers. Oxidation of formic acid on palladium
(Elsevier, 1978)
Catalytic effects of foreign metal monolayers deposited at underpotentials have been found for the oxidation of formic acid on palladium electrode. Palladium is known to form no poisoning species in oxidation of HCOOH. ...
On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media
(Elsevier, 1977)
The kinetics and mechanism have been investigated in the Cd(II)/Cd(Hg) system in 2 M NaClO4 + 1 M HClO4, at 25 ± 0.5°C. The galvanostatic single-pulse method has been used. The value of double-layer capacity, exchange ...
Electrochemical oxidation of formic acid at noble metals: Catalytic effects of foreign metal monolayers
(Elsevier, 1977)
The catalytic effects of a submonolayer of lead on noble metals have been shown and discussed in terms of a previously published model. A theoretical analysis of these effects is presented. It was demonstrated that foreign ...
Cohesive energy densities of poly(di‐n‐alkyl itaconates)
(Wiley, 1977)
The solubility parameters of the first ten members of the homologous series of poly(di‐n‐alkyl itaconates) were determined from limiting viscosity numbers in various organic solvents, differing in structure, polarity and ...
Multiphoton resonance absorption characteristics
(IOP Publishing, 1977)
It is shown that the Dyson equation gives finite values for multiphoton resonance absorption rates when an appropriate diagram summation technique is applied. A simple recurrence formula connects the n-photon absorption ...
Molybdenum and hydroxybenzene complexes in concentrated sulphuric acid
(Elsevier, 1976)
It is already known [1--5] that Ti, W, V, Mo and some other metals form
coloured complexes with 1,4-benzenediol in concentrated sulphuric acid. We
have also found that hydroxybenzene has similar properties. Papers found ...
Individual ionic activities and mass transfer in anodic chlorate formation
(Switzerland : Springer Nature, 1973)
The individual activity of hypochlorite ion in concentrated neutral salt (NaCl-NaClO3) solutions has been estimated kinetically by measurement of the Faradaic efficiency in a chlorate producing system comprised of a cell ...
Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions
(Pergamon Press, 1978)
The presence of metal ions (Cd2+, Mn2+, Zn2+), more electronegative than the cathodic potential for the hydrogen evolution reaction on iron in a 0.25M H2SO4 solution, inhibits the hydrogen evolution reaction and corrosion ...
Control of intramolecular γ-alkylation vs. α-alkylation of an αβ-unsaturated ketone: An unusual solvent effect
(Royal Society of Chemistry, 1979)
Most base-solvent combinations convert (2) into (3); γ-alkylation to yield (5) is effected by sodium hydroxide in dimethyl sulphoxide-water mixtures in which the water content is critical.
Acceleration of electrocatalytic reactions by pulsation of potential: Oxidation of formic acid on Pt and Pt/Pbads electrodes
(Pergamon Press, 1978)
Pulsating potential electrolysis has been applied to one typical electrocatalytic reaction ie, the oxidation of formic acid on platinum and platinum partially covered by lead adatoms electrodes. It has been found that much ...