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Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings
(American Chemical Society (ACS), 2007)
Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.
Ring-closing metathesis/fragmentation route to geometrically defined medium-ring cycloalkenes: Total synthesis of (+/-)-periplanone C
(American Chemical Society (ACS), 2004)
The combination of alkene metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium-ring cycloalkenes. The versatility of this method is demonstrated by the total synthesis of Periplanone C, a ...
A Novel Access to Tetrahydro β-Carbolines via One-Pot Hydroformylation / Fischer Indole Synthesis: Rearrangement of 3,3- Spiroindoleninium Cations
(American Chemical Society (ACS), 2008)
The two component one-pot hydroformylation/Fischer indole synthesis sequence of 2,5 dihydropyrroles and phenyl hydrazines allows a facile and convenient access to tetrahydro-β-carbolines in moderate to good yields.