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13,14-Seco-steroids: A New Type of Modified Steroids Containing a Nine-Membered Ring
(Wiley, 1999)
Oxidations of 14α‐hydroxy‐5α‐cholestan‐3β‐yl acetate (5) with lead tetraacetate under thermal or photolytic conditions or in the presence of iodine proceed mainly by fragmentation of the C(13)−C(14) bond to give as the ...