Now showing items 1-10 of 233
Utilization of fruit processing industry waste as green activated carbon for the treatment of heavy metals and chlorophenols contaminated water
(Elsevier Sci Ltd, Oxford, 2017)
Plum stones, as a part of industrial and municipal organic waste, were used as a precursor for preparation of a low-cost activated carbon. Engineered, thermochemically-modified adsorbent was used to remove lead (Pb2+), ...
Role of Spin State and Ligand Charge in Coordination Patterns in Complexes of 2,6-Diacetylpyridinebis(semioxamazide) with 3d-Block Metal Ions: A Density Functional Theory Study
(Amer Chemical Soc, Washington, 2013)
We report here a systematic computational study on the effect of the spin state and ligand charge on coordination preferences for a number of 3d-block metal complexes with the 2,6-diacetylpyridinebis(semioxamazide) ligand ...
Influence of manganese oxide on the activity of Pt/Al2O3 catalyst for CO and n-hexane oxidation
(Elsevier Science Bv, Amsterdam, 2006)
The influence of low loadings of MnOx on the catalytic activity for n-hexene and CO oxidation over highly dispersed Pt on alumina catalysts has been investigated. The applied deposition-precipitation method allows Mn to ...
Chemical stability of the peroxide bond enables diversified synthesis of potent tetraoxane antimalarials
(Amer Chemical Soc, Washington, 2008)
Of 17 prepared 1,2,4,5-tetraoxacyclohexanes stable to reductive and acidic conditions, 3 of them were more active than artemisinin against CQ and MFQ resistant strain TM91C235 and all compounds were more active in vitro ...
Stacking Interactions between Square-Planar Metal Complexes with 2,2'-Bipyridine Ligands. Analysis of Crystal Structures and Quantum Chemical Calculations
(Amer Chemical Soc, Washington, 2014)
Stacking interactions between square-planar metal complexes containing bipyridine ligands (bipy) were studied by analyzing data in the Cambridge Structural Database (CSD) and by density functional theory (DFT) calculations. ...
Substrate Stereocontrol in the Intramolecular Organocatalyzed Tsuji-Trost Reaction: Enantioselective Synthesis of Allokainates
(Amer Chemical Soc, Washington, 2014)
Organocatalyzed Tsuji-Trost cyclization of 3b proceeds with asymmetric induction and allows for stereoselective synthesis of (+)-allokainic acid. The stereochemical outcome of the cyclization was predicted by calculations.
Synergistic effect between non-ionic surfactant and halide ions in the forms of inorganic or organic salts for the corrosion inhibition of stainless-steel X4Cr13 in sulphuric acid
(Pergamon-Elsevier Science Ltd, Oxford, 2012)
The inhibition behaviour of the TRITON-X-405 mixed with KBr or C4H12NI in 2.0 M H2SO4 on the ferritic SS was studied using potentiodynamic and EIS measurements. The electrochemical data showed that mixtures used in this ...
Superior capacitive and electrocatalytic properties of carbonized nanostructured polyaniline upon a low-temperature hydrothermal treatment
(Pergamon-Elsevier Science Ltd, Oxford, 2013)
Carbonized nanostructured polyaniline (C.PANI) was hydrothermally treated in 1 mol dm(-3) KOH at 200 degrees C. The treatment caused significant reduction of micropore volume but negligible changes in mesoporous domain, ...
Analysis of the competitive adsorption and mass transfer influence on equilibrium mass fluctuations in affinity-based biosensors
We analyze the fluctuations of the equilibrium adsorbed mass in affinity-based biosensors, considering adsorption-desorption and mass transfer processes of two molecular species which compete for binding to the same probe ...
Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings
(Amer Chemical Soc, Washington, 2007)
Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.