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Relationships between structure and activity of carbon as a multifunctional support for electrocatalysts
(Royal Soc Chemistry, Cambridge, 2012)
We report on new insights into the relationships between structure and activity of glassy carbon (GC), as a model material for electrocatalyst support, during its anodization in acid solution. Our investigation strongly ...
Fine-tuning the feature size of nanoporous silver
(Royal Soc Chemistry, Cambridge, 2012)
We show that the characteristic ligament size of nanoporous Ag synthesized by chemical dissolution of Al from Ag-Al alloys can be tuned from the current submicrometer size (similar to 100-500 nm) down to a much smaller ...
Benchmarking density functional tight binding models for barrier heights and reaction energetics of organic molecules
(Wiley, Hoboken, 2017)
Density Functional Tight Binding (DFTB) models are two to three orders of magnitude faster than ab initio and Density Functional Theory (DFT) methods and therefore are particularly attractive in applications to large ...
Classification of stacking interaction geometries of terpyridyl square-planar complexes in crystal structures
(Royal Soc Chemistry, Cambridge, 2010)
Stacking interactions of terpyridyl square-planar complexes in crystal structures were studied analyzing data from the Cambridge Structural Database. In most of the crystal structures, two terpyridyl complexes were oriented ...
The role of spin states in the catalytic mechanism of the intra- and extradiol cleavage of catechols by O-2
(Royal Soc Chemistry, Cambridge, 2017)
Iron-dependent enzymes and biomimetic iron complexes can catalyze the ring cleavage of very inert, aromatic compounds. The mechanisms of these transformations and the factors that lead either to extradiol cleavage or ...
The electrochemical reduction of trinitrotoluene on a platinum wire modified by chemisorbed acetonitrile
(Elsevier, 2010)
The electrochemical reduction of 2,4,6-trinitrotoluene (TNT) was investigated by cyclic voltammetry on a platinum electrode in aqueous sodium chloride solutions with acetonitrile containing different concentrations of TNT. ...
In situ STM study of nanosized Ru and Os islands spontaneously deposited on Pt(111) and Au(111) electrodes
(Elsevier, 2004)
We provide an overview of structure and reactivity of selected bimetallic single crystal electrodes obtained by the method of spontaneous deposition. The surfaces that are described and compared are the following: Au(111)/Ru, ...
Effect of Candida antarctica Lipase B Immobilization on the Porous Structure of the Carrier
(Wiley-V C H Verlag Gmbh, Weinheim, 2011)
A series of poly(GMA-co-EGDMA) resins with identical composition but varying particle sizes, pore radii, specific surface areas and specific volumes are studied to assess how Candida antarctica lipase B immobilization ...
Polarization curves in the ohmic controlled electrodeposition of metals
(Oxford : Pergamon-Elsevier Science Ltd, 2009)
The conditions under which ohmic controlled metal electrodeposition occurs are discussed using a simple mathematical model. it is shown that ohmic controlled electrodeposition can be operative if the value of the exchange ...
Water-soluble main ions in precipitation over the southeastern Adriatic region: chemical composition and long-range transport
(Springer Heidelberg, Heidelberg, 2010)
Precipitation samples collected from 1995 to 2000 at meteorological station in the eastern outskirts of Herceg Novi (Montenegro) were analysed on Na(+), K(+), Mg(2+), Ca(2+), Cl(-), SO(4) (2-), NO(3) (-) and NH(4) (+). ...